Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Title: Understanding C-H Bond Strength in Cyclopentene**
**Objective:**
- Analyze the different C-H bonds in cyclopentene.
- Rank these C-H bonds based on their bond strength, from weakest to strongest.
**Molecular Structure:**
- The diagram depicts the molecular structure of cyclopentene.
- Cyclopentene is a five-membered carbon ring with a single double bond.
**Analysis:**
1. **Identify C-H Bonds:**
- Cyclopentene consists of several C-H bonds attached to the carbon atoms in the ring.
- Each carbon atom in the ring can form bonds with hydrogen atoms, resulting in a combination of sp² and sp³ hybridized C-H bonds.
2. **Hybridization and Bond Strength:**
- Bond strength is influenced by the hybridization of the carbon atoms:
- sp² hybridization (found in alkenes) typically involves stronger bonds due to greater s-character compared to sp³.
- sp³ hybridized carbon atoms (as in alkanes) have weaker C-H bonds.
3. **Ranking Bonds:**
- C-H bonds attached to sp² hybridized carbons are usually stronger than those attached to sp³.
- Therefore, bonds on the carbons participating in the double bond are stronger than those on the single bonds.
4. **Conclusion:**
- Rank the C-H bonds in cyclopentene, starting from those on sp³ hybridized carbons as the weakest to those on sp² hybridized carbons as the strongest.
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