1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)- 1,4-dichloro-2-butene. a. Label the 1,2-addition product and the 1,4-addition product. b. Label the kinetic product and the thermodynamic product. c. Explain why one product is favoured at higher temperatures and the other is favoured at lower temperatures.
1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)- 1,4-dichloro-2-butene. a. Label the 1,2-addition product and the 1,4-addition product. b. Label the kinetic product and the thermodynamic product. c. Explain why one product is favoured at higher temperatures and the other is favoured at lower temperatures.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major
product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)-
1,4-dichloro-2-butene.
a. Label the 1,2-addition product and the 1,4-addition product.
b. Label the kinetic product and the thermodynamic product.
c. Explain why one product is favoured at higher temperatures and the other is
favoured at lower temperatures.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcf37c42b-cb3b-48a0-8048-6dbd68b25d2b%2F693a72fd-b811-426b-84c5-5418d1468f06%2Facwl9dg_processed.png&w=3840&q=75)
Transcribed Image Text:1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major
product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)-
1,4-dichloro-2-butene.
a. Label the 1,2-addition product and the 1,4-addition product.
b. Label the kinetic product and the thermodynamic product.
c. Explain why one product is favoured at higher temperatures and the other is
favoured at lower temperatures.
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