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1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)- 1,4-dichloro-2-butene. a. Label the 1,2-addition product and the 1,4-addition product. b. Label the kinetic product and the thermodynamic product. c. Explain why one product is favoured at higher temperatures and the other is favoured at lower temperatures.

1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)- 1,4-dichloro-2-butene. a. Label the 1,2-addition product and the 1,4-addition product. b. Label the kinetic product and the thermodynamic product. c. Explain why one product is favoured at higher temperatures and the other is favoured at lower temperatures.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)- 1,4-dichloro-2-butene. a. Label the 1,2-addition product and the 1,4-addition product. b. Label the kinetic product and the thermodynamic product. c. Explain why one product is favoured at higher temperatures and the other is favoured at lower temperatures.
Transcribed Image Text:1,3-butadiene reacting with Cl2 in CH2C12 results in 3,4-dichloro-1-butene as major product at -80°C, while if these reagents are mixed at 40°C, the major product will be (E)- 1,4-dichloro-2-butene. a. Label the 1,2-addition product and the 1,4-addition product. b. Label the kinetic product and the thermodynamic product. c. Explain why one product is favoured at higher temperatures and the other is favoured at lower temperatures.
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