13) A solution was made by dissolving 4.05 g of a solute in 130:9 g of acetone. The solution boiled at 56.58 79 C. The boiling point of pure acetone is 55.95° C, and the Ks-1.71° C/m. What is the molecular weight of the solute? A) 80.3 B) 105 C) 12.7 D) 140 14) The decomposition of N₂Os(g)->NO₂(g) + NO3(g) proceeds as a first order reaction with a half-life of 30.0 seconds at a certain temperature. If the initial concentration [N:Oslo 0.400 M, what is the concentration after 150 seconds? A) 0.400 M B) 0.100 M C) 0.025 M D) 0.013 M 15) Which equation below best gives the concentration of N:Os versus time in the previous question Q14? A) [N20s] ([N20s]0)/t1/2 B) [N20s] = kt C) [N20s]-[N2Osloe D) 1/[N20s] =1/[N20s]+ kt min-¹ at 57 K. What is the D) 1200 min = 16) The rate constant for the first order reaction A---> B+C is k-2.2 x 10 half-life for this reaction at 57 K? A) 9.1 min B) 32 min 17) Calculate AH° for the reaction: 2C) + 2H₂O(g) ---> -> C) + H₂O H₂(g) + CO2(g) CH4) + H₂O(g) C) 64 min CH4 + CO2(g) AH-150 kJ AH-41kJ ΔΗ°==-206}J (1) CO(g) + H₂ (8) (2) CO(g) + H₂O(g) ---> (3) CO(g) + 3H₂(g) ---> A) 53 kJ B) 116 kJ C) -372 kJ D)-116 kJ 18) When a strong acid is titrated with a weak base, the pH at the equivalence point is ALWAYS A) <7 B) 7 9)>7 D) <1 19) Which is the weakest intermolecular force among a group of molecules of comparable molar mass? A) Dipole-dipole B) London C) Ionic bonding D) Hydrogen bonding 20) Given: N₂(g) + 3 H₂(g) <-> 2 NH³(g) At equilibrium at a certain temperature, the concentration of NH3(g), H₂(g) and N₂(g) are 0.490 M, 1.41 M and 0.14 M, respectively. Calculate the value of Ke for this reaction. A) 1.26 B) 3.02 C) 0.612 D) 1.96 21) Which one of these statements about strong base is true A) Strong bases produce solutions with a higher pH than weak bases B) Bases have only the OH group in their structure C) Strong bases are very concentrated acids D) Strong bases are 100% ionized in water 22) Consider the reaction represented by the equation: Fe³+ (aq) + SCN- (aq) → FeSCN²+ (aq) 6.00 M Fe³+ (aq) and 10.0 M SCN (aq) are mixed at a certain temperature and at equilibrium the concentration of FeSCN2+ (aq) is 2.50 M. A) 295x10-3 B) 303 x104 D) 95 x10³ C) 250 x104 23) Consider the following reaction: 4 PCB(g)-> P4(g) + 6 Cl2(g) If the initial concentration of PC13(g) is 3.0 M, and "x" is the equilibrium concentration of P4(g), what is the correct equilibrium relation? A) Kc = 6x7 B) Kc=6x7/(3.0-x)* D) Kc=x7/(3.0-x)* D) 1.39 g/L D) 0.0104 C) Kc = (x)(6x)/(3.0-4x)* 24) What is the density of NH3 at 5 atm pressure and a temperature of 35°C? C) 0.980 g/L B) 3.36 g/L A) 16.6 g/L M 75) What is the pH of 80.0 M aqueous solution of NH3 (ammonia). It's Kb = 1.8 x 10. C) 0.778