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12.62 Devise a synthesis of each compound from the indicated starting material, organic compounds containing one or two carbons, and any other required reagents. a. C. H-CEC-H OH b. d. H-C C- | H. (+ enantiomer)

12.62 Devise a synthesis of each compound from the indicated starting material, organic compounds containing one or two carbons, and any other required reagents. a. C. H-CEC-H OH b. d. H-C C- | H. (+ enantiomer)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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can you solve 12.62. It says " devise a synthesis of each compound from the indicated starting material,organic compounds containing one or two carbons, and any other requried reagents." 

510 Chapter 12 Oxidation and Reduction Devise a synthesis of compound A from the given starting materials. You may use any other inoganic reagents or organic alcohols. A was used to prepare aliskiren, a drug used to treat hypertension (see also Problem 12.61 5.7). CH30. Но. CHO Br CH30 CH30 Br Br NH2 OH CH30. H2N. CH30 aliskiren 12.62 Devise a synthesis of each compound from the indicated starting material, organic compounds containing one or two carbons, and any other required reagents. OH a. C. H-C C-H b be AMinebi rast b. d. H-C C-H H. (+ enantiomer) 12.63 Devise a synthesis of each compound from the indicated starting material. You may use any other needed organic or inorganic reagents. Br a. НО b. OH HO. 12.64 Devise a synthesis of (3R,4S)-3,4-dichlorohexane from acetylene and any needed organic compounds or inorganic reagents. 12.65 Devise a synthesis of each compound from CH3CH2OH as the only organic starting material; that is, every carbon in the product must come from a molecule of ethanol. You may use any other needed inorganic reagents. OH a. b. C. OH 12.66 Devise a synthesis of A from the three starting materials given. You may use any other needed organic or inorganic reagents. HO Spectroscopy Problems 12.67 and 12.68 are intended for students who have already learned about spectroscopy in Chapters A-C. Treatment of alcohol A (molecular formula CgH120) with CrO3, H2SO4, and H20 affords B with molecular formula CsH1,0. which gives an IR absorption at 1718 cm. The 'H NMR spectrum of B contains the following signals: 1.10 (doublet, 6 H). 2.14 (singlet, 3 H), and 2.58 (septet, 1 H) ppm. What are the structures of A and R1 12.67
Transcribed Image Text:510 Chapter 12 Oxidation and Reduction Devise a synthesis of compound A from the given starting materials. You may use any other inoganic reagents or organic alcohols. A was used to prepare aliskiren, a drug used to treat hypertension (see also Problem 12.61 5.7). CH30. Но. CHO Br CH30 CH30 Br Br NH2 OH CH30. H2N. CH30 aliskiren 12.62 Devise a synthesis of each compound from the indicated starting material, organic compounds containing one or two carbons, and any other required reagents. OH a. C. H-C C-H b be AMinebi rast b. d. H-C C-H H. (+ enantiomer) 12.63 Devise a synthesis of each compound from the indicated starting material. You may use any other needed organic or inorganic reagents. Br a. НО b. OH HO. 12.64 Devise a synthesis of (3R,4S)-3,4-dichlorohexane from acetylene and any needed organic compounds or inorganic reagents. 12.65 Devise a synthesis of each compound from CH3CH2OH as the only organic starting material; that is, every carbon in the product must come from a molecule of ethanol. You may use any other needed inorganic reagents. OH a. b. C. OH 12.66 Devise a synthesis of A from the three starting materials given. You may use any other needed organic or inorganic reagents. HO Spectroscopy Problems 12.67 and 12.68 are intended for students who have already learned about spectroscopy in Chapters A-C. Treatment of alcohol A (molecular formula CgH120) with CrO3, H2SO4, and H20 affords B with molecular formula CsH1,0. which gives an IR absorption at 1718 cm. The 'H NMR spectrum of B contains the following signals: 1.10 (doublet, 6 H). 2.14 (singlet, 3 H), and 2.58 (septet, 1 H) ppm. What are the structures of A and R1 12.67
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