12.3 Show that the minimum cation-to-anion radius ratio for a coordination number of 6 is 0.414. (Hint: Use the NaCl crystal structure in Figure 12.2, and assume that anions and cations are just touching along cube edges and across face diagonals.)

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12.3 Show that the minimum cation-to-anion radius
ratio for a coordination number of 6 is 0.414. (Hint:
Use the NaCl crystal structure in Figure 12.2, and
assume that anions and cations are just touching
along cube edges and across face diagonals.)
Transcribed Image Text:12.3 Show that the minimum cation-to-anion radius ratio for a coordination number of 6 is 0.414. (Hint: Use the NaCl crystal structure in Figure 12.2, and assume that anions and cations are just touching along cube edges and across face diagonals.)
Figure 12.22 The
aluminum oxide-chromium
Composition (mol% Cr203)
20
40
60
80
100
2300
oxide phase diagram.
(Adapted from E. N. Bunting,
"Phase Equilibria in the System
Cr,O3-Al,O3," Bur. Standards
J. Research, 6, 1931, p. 948.)
2275 + 25°C
Liquid
4000
2200
Liquid + Solid Solution
2100
3800
2045 + 5°C
2000
Al203–Cr203 Solid Solution
3600
20
40
60
80
100
(Al203)
(Cr203)
Composition (wt% Cr2O3)
Temperature (°C)
Temperature (°F)
Transcribed Image Text:Figure 12.22 The aluminum oxide-chromium Composition (mol% Cr203) 20 40 60 80 100 2300 oxide phase diagram. (Adapted from E. N. Bunting, "Phase Equilibria in the System Cr,O3-Al,O3," Bur. Standards J. Research, 6, 1931, p. 948.) 2275 + 25°C Liquid 4000 2200 Liquid + Solid Solution 2100 3800 2045 + 5°C 2000 Al203–Cr203 Solid Solution 3600 20 40 60 80 100 (Al203) (Cr203) Composition (wt% Cr2O3) Temperature (°C) Temperature (°F)
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