12.25. A mixture containing species 1 with a dilute amount of species 2 is found to obey Raoult's law, yP1 Dvap x1Pi ', near xA 1 but not at other compositions. Show that the solution then also obeys Henry's law for species 2 whenever it obeys Raoult's law for species 1, with the former being given by У»Р2 3D К х2 where Henry's constant K depends on temperature and pressure but not on composition. That is, show that Raoult's law and Henry's law imply each other.
12.25. A mixture containing species 1 with a dilute amount of species 2 is found to obey Raoult's law, yP1 Dvap x1Pi ', near xA 1 but not at other compositions. Show that the solution then also obeys Henry's law for species 2 whenever it obeys Raoult's law for species 1, with the former being given by У»Р2 3D К х2 where Henry's constant K depends on temperature and pressure but not on composition. That is, show that Raoult's law and Henry's law imply each other.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:12.25. A mixture containing species 1 with a dilute amount of species 2 is found to obey
Raoult's law, yP1
Dvap
x1Pi
', near xA
1 but not at other compositions. Show that
the solution then also obeys Henry's law for species 2 whenever it obeys Raoult's
law for species 1, with the former being given by
У»Р2 3D К х2
where Henry's constant K depends on temperature and pressure but not on
composition. That is, show that Raoult's law and Henry's law imply each other.
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