12. Which reagent(s), if any, may be used to carry out the following reaction? 1.NaCN 2. HCI/H₂O I OH 1. LIAIH4 2. H₂O II OCH3 I CrO3 H₂SO4 III II 13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with a metal hydride? OH ď III KMnO4 H* IV CHO OH Ho IV 14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal. OCH 3 OCH₂CH3 CH3-C-H CH3-CH₂-C-OCH3 CH3 CH₂ CH EEE CH3 II 1. NaOH 2. H₂O V III OCH₂CH3 OH CH3 C OCH 3 CH3 IV

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Chapter1: Chemical Foundations
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12. Which reagent(s), if any, may be used to carry out the following reaction?
1.NaCN
2. HCI/H₂O
I
1. LIAIH4
2. H₂O
II
OH
لوله
OH
I
13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with a
metal hydride
II
CrO3
H₂SO4
III
CH3
III
II
KMnO4
H*
CHO
IV
14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal.
OCH 3
OH
IV
OCH₂CH3
att fot
CH3 C-H CH3 CH₂ C OCH 3
CH3–CH,CH CH3 C OCH ₂
OCH3
OCH₂CH3
CH3
1. NaOH
2. H₂O
V
لوية
III
OH
IV
Transcribed Image Text:12. Which reagent(s), if any, may be used to carry out the following reaction? 1.NaCN 2. HCI/H₂O I 1. LIAIH4 2. H₂O II OH لوله OH I 13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with a metal hydride II CrO3 H₂SO4 III CH3 III II KMnO4 H* CHO IV 14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal. OCH 3 OH IV OCH₂CH3 att fot CH3 C-H CH3 CH₂ C OCH 3 CH3–CH,CH CH3 C OCH ₂ OCH3 OCH₂CH3 CH3 1. NaOH 2. H₂O V لوية III OH IV
لية بهية
8. Rank the following compounds in order of increasing solubility in hexane:
I
I
I
9. Which of the following alcohols can be oxidized to a ketone using Na2Cr2O7/H2SO4? (3 pts)
OH
.OH
OH
1.CH3MgBr
2. H2O
.OH
II
10. Which of the following compounds is not likely to be oxidized?
II
OH
1. CH₂Br
2. HO
II
II
III
OH
الجبنه
III
NazCraO
H2SO4
III
III
OH
11. Which reagent(s), if any, may be used to carry out the following reaction?
ai-ai
CH3OH
H+
IV
IV
OH
IV
H2O
H*
V
IV
L
Transcribed Image Text:لية بهية 8. Rank the following compounds in order of increasing solubility in hexane: I I I 9. Which of the following alcohols can be oxidized to a ketone using Na2Cr2O7/H2SO4? (3 pts) OH .OH OH 1.CH3MgBr 2. H2O .OH II 10. Which of the following compounds is not likely to be oxidized? II OH 1. CH₂Br 2. HO II II III OH الجبنه III NazCraO H2SO4 III III OH 11. Which reagent(s), if any, may be used to carry out the following reaction? ai-ai CH3OH H+ IV IV OH IV H2O H* V IV L
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