12. Which reagent(s), if any, may be used to carry out the following reaction?1.NaCN2. HCI/H₂OI1. LIAIH42. H₂OIIOHلولهOHI13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with ametal hydrideIICrO3H₂SO4IIICH3IIIIIKMnO4H*CHOIV14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal.OCH 3OHIVOCH₂CH3att fotCH3 C-H CH3 CH₂ C OCH 3CH3–CH,CH CH3 C OCH ₂OCH3OCH₂CH3CH31. NaOH2. H₂OVلويةIIIOHIV لية بهية8. Rank the following compounds in order of increasing solubility in hexane:III9. Which of the following alcohols can be oxidized to a ketone using Na2Cr2O7/H2SO4? (3 pts)OH.OHOH1.CH3MgBr2. H2O.OHII10. Which of the following compounds is not likely to be oxidized?IIOH1. CH₂Br2. HOIIIIIIIOHالجبنهIIINazCraOH2SO4IIIIIIOH11. Which reagent(s), if any, may be used to carry out the following reaction?ai-aiCH3OHH+IVIVOHIVH2OH*VIVL

Here oxidation, reduction,esterification , carbonyl protection have been discussed.

12. Which reagent(s), if any, may be used to carry out the following reaction? 1.NaCN 2. HCI/H₂O I OH 1. LIAIH4 2. H₂O II OCH3 I CrO3 H₂SO4 III II 13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with a metal hydride? OH ď III KMnO4 H* IV CHO OH Ho IV 14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal. OCH 3 OCH₂CH3 CH3-C-H CH3-CH₂-C-OCH3 CH3 CH₂ CH EEE CH3 II 1. NaOH 2. H₂O V III OCH₂CH3 OH CH3 C OCH 3 CH3 IV

12. Which reagent(s), if any, may be used to carry out the following reaction? 1.NaCN 2. HCI/H₂O I OH 1. LIAIH4 2. H₂O II OCH3 I CrO3 H₂SO4 III II 13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with a metal hydride? OH ď III KMnO4 H* IV CHO OH Ho IV 14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal. OCH 3 OCH₂CH3 CH3-C-H CH3-CH₂-C-OCH3 CH3 CH₂ CH EEE CH3 II 1. NaOH 2. H₂O V III OCH₂CH3 OH CH3 C OCH 3 CH3 IV

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

12. Which reagent(s), if any, may be used to carry out the following reaction?
1.NaCN
2. HCI/H₂O
I
1. LIAIH4
2. H₂O
II
OH
لوله
OH
I
13. What ketone or aldehyde is needed to prepare the alcohol shown below by reduction with a
metal hydride
II
CrO3
H₂SO4
III
CH3
III
II
KMnO4
H*
CHO
IV
14. Classify each of the following compounds as a(n) acetal, ketal, hemiacetal, or hemiketal.
OCH 3
OH
IV
OCH₂CH3
att fot
CH3 C-H CH3 CH₂ C OCH 3
CH3–CH,CH CH3 C OCH ₂
OCH3
OCH₂CH3
CH3
1. NaOH
2. H₂O
V
لوية
III
OH
IV

لية بهية
8. Rank the following compounds in order of increasing solubility in hexane:
I
I
I
9. Which of the following alcohols can be oxidized to a ketone using Na2Cr2O7/H2SO4? (3 pts)
OH
.OH
OH
1.CH3MgBr
2. H2O
.OH
II
10. Which of the following compounds is not likely to be oxidized?
II
OH
1. CH₂Br
2. HO
II
II
III
OH
الجبنه
III
NazCraO
H2SO4
III
III
OH
11. Which reagent(s), if any, may be used to carry out the following reaction?
ai-ai
CH3OH
H+
IV
IV
OH
IV
H2O
H*
V
IV
L

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