12. i. What is the function of the burette in a volumetric titration? ii. What is the pH when 49.00 mL of 0.100 M NaOH solution have been added to 50.00 mL of 0.100 M HCl solution? toinad Cran 4.25.00 of this compla in

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
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Problem 12.97PAE
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Basic analytic chemistry - volumetry analysis
12.
i.
What is the function of the burette in a volumetric titration?
ii.
What is the pH when 49.00 mL of 0.100 M NaOH solution have been added to
50.00 mL of 0.100 M HCl solution?
iii.
A sample contained Cr(III) species. A 25.00 mL portion of this sample is
combined with 10.00 mL of a 0.0875 M solution that contains a complexing
agent, CDTA. This mixture is heated to boiling for several minutes to allow the
CDTA to complex with Cr(III) species. The mixture is then cooled, and the
excess CDTA is measured by a back titration using 0.0258 M Bi3+, requiring
4.20 mL to reach the end point. What was the original concentration of Cr(III)
species in the sample? [Molar ratio of CDTA:Cr(III): Bi³+ = 1:1:1]
Transcribed Image Text:12. i. What is the function of the burette in a volumetric titration? ii. What is the pH when 49.00 mL of 0.100 M NaOH solution have been added to 50.00 mL of 0.100 M HCl solution? iii. A sample contained Cr(III) species. A 25.00 mL portion of this sample is combined with 10.00 mL of a 0.0875 M solution that contains a complexing agent, CDTA. This mixture is heated to boiling for several minutes to allow the CDTA to complex with Cr(III) species. The mixture is then cooled, and the excess CDTA is measured by a back titration using 0.0258 M Bi3+, requiring 4.20 mL to reach the end point. What was the original concentration of Cr(III) species in the sample? [Molar ratio of CDTA:Cr(III): Bi³+ = 1:1:1]
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