12. From the data in Table 4–3 determine at 25°C: (a) The amount of heat which will be liberated when 2 moles of H;S0,(1) are dissolved in 30 moles of H20(1) (b) The differential heats of solution of the acid and the water for the given solution.

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TABLE 4-3. INTEGRAL AND DIFFERENTIAL HEATS OF SOLUTION
FOR 1 MOLE oF H,SO, IN WATER AT 25°C
ΔΗ
Moles of
Water (ni)
AH,
(cal/mole)
AH,
(cal/mole)
(cal)
-6,750
-6,740
-4,730
-2,320
-1,480
-1,040
-570
0.50
-3,810
-6,820
-9,960
-11,890
- 13,120
-14,740
- 16,240
- 16,990
-17,470
- 17,770
- 18,130
- 18,990
- 20,050
- 22,990
-438
-2,090
-5,320
-7,450
-8,960
-11,320
-13,910
-15,640
- 16,860
-17,480
-17,700
- 18,260
- 19,220
- 22,990
1
2
3
4
6.
- 233
- 89.8
10
15
25
-24.4
50
-5.70
200
-2.16
800
-0.91
3,200
-0.26
Transcribed Image Text:TABLE 4-3. INTEGRAL AND DIFFERENTIAL HEATS OF SOLUTION FOR 1 MOLE oF H,SO, IN WATER AT 25°C ΔΗ Moles of Water (ni) AH, (cal/mole) AH, (cal/mole) (cal) -6,750 -6,740 -4,730 -2,320 -1,480 -1,040 -570 0.50 -3,810 -6,820 -9,960 -11,890 - 13,120 -14,740 - 16,240 - 16,990 -17,470 - 17,770 - 18,130 - 18,990 - 20,050 - 22,990 -438 -2,090 -5,320 -7,450 -8,960 -11,320 -13,910 -15,640 - 16,860 -17,480 -17,700 - 18,260 - 19,220 - 22,990 1 2 3 4 6. - 233 - 89.8 10 15 25 -24.4 50 -5.70 200 -2.16 800 -0.91 3,200 -0.26
12. From the data in Table 4-3 determine at 25°C:
(a) The amount of heat which will be liberated when 2 moles of H,S0,(1)
are dissolved in 30 moles of H,0(1)
(b) The differential heats of solution of the acid and the water for the given
solution.
Transcribed Image Text:12. From the data in Table 4-3 determine at 25°C: (a) The amount of heat which will be liberated when 2 moles of H,S0,(1) are dissolved in 30 moles of H,0(1) (b) The differential heats of solution of the acid and the water for the given solution.
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