12. A typical car/truck battery is a cell made by transferring 2 e- by a reaction between lead and sulfuric acid. If the voltage produced (Eºcell) is 12 V, what is AG° of this reaction at 25° C? AG° =

12. A typical car/truck battery is a cell made by transferring 2 e- by a reaction between lead and sulfuric acid. If the voltage produced (Eºcell) is 12 V, what is AG° of this reaction at 25° C? AG° =

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Consider the galvanic cell based on the following half-reactions. Ag+ + e− → Ag ℰ° = +0.80 V Fe2+ + 2 e− → Fe ℰ° = −0.44 V (a) Determine the overall cell reaction and calculate ℰ ° cell . (b) Calculate ΔG° and K for the cell reaction at 25°C. (c) Calculate ℰcell at 25°C when [Ag+ ] = 1.0 ✕ 10−4 M and [Fe2+ ] = 1.0 ✕ 10−2 M.
A certain metal M forms a soluble nitrate salt MNO,. Suppose the left half cell of a galvanic cell apparatus is filled with a 3.50 M solution of MNO, and the right half cell with a 17.5 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. left x10 Which electrode will be positive? right What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.
Galvanic cell has 2 half reactions O2(g) + 4H+(aq) + 4e- → 2H2O(l) E0red = +1.23 V Cr3+(aq) + 3e- → Cr(s) E0red = -0.74 V Write a balanced equation that describes the cell, ensuring that E0cell > 0 V and Calculate E0cell
A certain metal M forms a soluble nitrate salt MNO3. Suppose the left half cell of a galvanic cell apparatus is filled with a 175. mM solution of MNO3 and the right half cell with a 3.50 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right ■ □x10 X S
A certain metal M forms a soluble sulfate salt M₂SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 2.00 M solution of M₂SO4 and the right half cell with a 10.0 mM solution of the same substance. Electrodes made M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. V left right x10 X T
A certain half-reaction has a standard reduction potential Ered=-0.64 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 1.20 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. ロ→ロ 7² 0 Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? yes, there is a minimum. = v If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. no minimum X S ? Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? O yes, there is a maximum. ☐v If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximum By using the information in…
Can you break down the problem attached?
A galvanic cell is prepared using copper and silver. Its cell notation is shown below: Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s) Which of the following processes occurs at the cathode? A. Cu(s) → Cu2+(aq) + 2e- B. Cu2+(aq) + 2e- → Cu(s) C. Ag+(aq) + e- → Ag(s) D. Ag(s) → Ag+(aq) + e- E. Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s) Copper is electroplated from a CuSO4 solution. A constant current of 4.54 A is applied by an external power supply. How long (minutes) will it take to deposit 0.985 g of Cu? (the answer should be entered with 3 significant figures; do not enter units; give answer in normal notation--examples include 1.23 and 120. and -123 and 123. and 12.3) DOnt need work shown just answer asap Predict the sign of ΔSorxn (positive or negative) for the following reactions: CH3OH(l) → CH3OH(s) CH4(g) + H2O(g) → CO(g) + 3…
Calculate the concentration of an unknown solution in a concentration cell. A concentration cell consisting of two hydrogen electrodes (P H2- latm), where the cathode is a standard hydrogen electrode and the anode solution has an unknown pH, has a cell voltage of 0.193 V. What is the pH in the unknown solution? Assume the temperature of the solutions is 298 K. !! pH =
Questions 20 and 21 refer to the following information. Galvanic Cell Cell Diagram E°cell (Volts) Mg | Mg2(1.0 M) || Pb*2(1.0 M) | Pb 1 2.24 Zn | Zn(1.0 M) || Pb*2(1.0 M) | Pb 2 0.63 Mg | Mg*(1.0 M) || Zn*2(1.0 M) | Zn 3 The chemical reaction occurring in first galvanic cell is: Mg + Pb*2 → Mg+2 + Pb 21. If the concentration of Mg+2 is changed from 1.0 M to 3.0 M in the galvanic cells above, what will happen to the observed cell voltages in galvanic cells 1 and 3? (A) The voltage in both galvanic cells 1 and 3 will increase. (B) The voltage will decrease in both galvanic cells 1 and 3. (C) The voltage in galvanic cell 1 will increase and will decrease in galvanic cell 3 (D) The voltage in galvanic cell 3 will increase and will decrease in galvanic cell 1. 22. Consider a voltaic cell based on these half-cells. Ag (aq) +e → Ag/s) Cd (aq) + 2e → Cd¢s) E* = +0.80 V E = -0.40 V Identify the anode and give the voltage of this cell under standard conditions. (A) Ag; Ecell = 0.40 V (B) Ag;…
Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of these
3. The oxidation of methanol, as described by the equation below, has a AG value of -937.9 kJ/mol. What is the standard cell potential for a methanol fuel cell? 2CH3OH +30₂ → 2CO₂ + 4H₂O