11.13 At standard temperature and pressure, the molar volumes of Cl2 and NH3 gases are 22.06 and 22.40 L, respectively. (a) Given the different molecular weights, dipole moments, and molecular shapes, why are their molar volumes nearly the same? (b) On cooling to 160 K, both substances form crystalline solids. Do you expect the molar volumes to decrease or increase on cooling the gases to 160 K? (c) The densities of crystalline Cl2 and NH3 at 160 K are 2,02 and 0.84 g/cm3, respectively. Calculate their molar volumes (d) Are the molar volumes in the solid state as similar as they are in the gaseous state? Explain. (e) Would you expect the molar volumes in the liquid state to be closer to those in the solid or gaseous state? an u er

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

d and e

11.13 At standard temperature and pressure, the molar volumes
of Cl2 and NH3 gases are 22.06 and 22.40 L, respectively.
(a) Given the different molecular weights, dipole moments,
and molecular shapes, why are their molar volumes nearly
the same? (b) On cooling to 160 K, both substances form
crystalline solids. Do you expect the molar volumes to
decrease or increase on cooling the gases to 160 K? (c) The
densities of crystalline Cl2 and NH3 at 160 K are 2,02 and
0.84 g/cm3, respectively. Calculate their molar volumes
(d) Are the molar volumes in the solid state as similar as
they are in the gaseous state? Explain. (e) Would you expect
the molar volumes in the liquid state to be closer to those
in the solid or gaseous state?
an
u
er
Transcribed Image Text:11.13 At standard temperature and pressure, the molar volumes of Cl2 and NH3 gases are 22.06 and 22.40 L, respectively. (a) Given the different molecular weights, dipole moments, and molecular shapes, why are their molar volumes nearly the same? (b) On cooling to 160 K, both substances form crystalline solids. Do you expect the molar volumes to decrease or increase on cooling the gases to 160 K? (c) The densities of crystalline Cl2 and NH3 at 160 K are 2,02 and 0.84 g/cm3, respectively. Calculate their molar volumes (d) Are the molar volumes in the solid state as similar as they are in the gaseous state? Explain. (e) Would you expect the molar volumes in the liquid state to be closer to those in the solid or gaseous state? an u er
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Phase Diagrams
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY