11. An adsorption of phosphorous, P4, on Pt surface goes with dissociation process to P atoms as: (-s- represents the surface site) then the Langmuir isotherm P4 +4-s- 2 4 P-s- equation is: *

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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11. An adsorption of phosphorous, P4, on Pt
surface goes with dissociation process to P
atoms as:
(-s- represents the
surface site) then the Langmuir isotherm
P4 +4 -s- 24 P-s-
equation is: *
Coverage = K°*25[P]0#25/(1+K°*25[p]0%25)
Coverage = K°*4[P]0*4/(1+K°*4[P]°*4)
coverage = Kª[P]4/(1+K*[p]*)
Coverage = K[P]/1+K[P]
Coverage = K°*33[P]0*33/(1+K°*33[p]O%33)
Transcribed Image Text:11. An adsorption of phosphorous, P4, on Pt surface goes with dissociation process to P atoms as: (-s- represents the surface site) then the Langmuir isotherm P4 +4 -s- 24 P-s- equation is: * Coverage = K°*25[P]0#25/(1+K°*25[p]0%25) Coverage = K°*4[P]0*4/(1+K°*4[P]°*4) coverage = Kª[P]4/(1+K*[p]*) Coverage = K[P]/1+K[P] Coverage = K°*33[P]0*33/(1+K°*33[p]O%33)
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