11), a) How many different molecules containing one double bond can be used to synthesize 4-methyl-4-heptanol (as the major product) via acid catalyzed hydration with HISO and H,0? Draw them all below. b) Are any of the structures in part (a) trisubstituted alkenes? If so, redraw irthem below. c) Label (f possible) the structure(s) in part (b) as either Z or E double bond isomers.
11), a) How many different molecules containing one double bond can be used to synthesize 4-methyl-4-heptanol (as the major product) via acid catalyzed hydration with HISO and H,0? Draw them all below. b) Are any of the structures in part (a) trisubstituted alkenes? If so, redraw irthem below. c) Label (f possible) the structure(s) in part (b) as either Z or E double bond isomers.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:11)
a) How many different molecules containing one double bond can be used to synthesize
4-methyl-4-heptanol (as the major product) via acid catalyzed hydration with H2SOe and
H20? Draw them all below.
b) Are any of the structures in part (a) trisubstituted alkenes? If so, redraw it/them
below.
c) Label (if possible) the structure(s) in part (b) as either Z or E double bond isomers.
Bonus Question:
) Recently, the Gademann research group from the University of Zurich,
completed the synthesis of (+)-Peyssonnosol, a complex natural product (shown below
on the left) which contains seven stereocenters. Briefly describe what the "(t)" symbol in
front of the synthesized natural product name means.
Me.,
Me,
Me Me
HO.
Me
Me
Synthesized
()-Peyssonnosol
Starting Materials Used
inSynthesis
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