10/11 The first step in the production of high purity silicon for The first step in the production of high purity silicon for semiconductors is represented by this equation: SiO2{s) + 2C(s) –→ Si(s) + 2CO(g) A H° = 689.9 kJ semiconductors is represented by this equation: SIO2(s) + 2C( Si(s) + 2CO(g) A Hº = 689.9 kJ Find A Srxn° for the production of pure silicon, given the following data: S° for C = 5.7 J/mol*K, for CO = 197.6 J/mol*K, for Si = 18.8 Using the value of A Srxnº you calculated from question 10, determine A G° for the reaction at 25 °C. J/mol*K and for SIO2 = 41.8 J/mol*K. O J/mol*K O 329.1 kJ/mol 360.8 J/mol"K 582.3 kJ/mol O 2314 J/mol*K O O KJ/mol O -360.8 J/mol*K O 106.8 kJ/mol O 168.9 J/mol*K -106.8 kJ/mol 33. The first step in the production of high purity silicon for semiconductors is represented by this equation: SiO2(s) + 2C(s) – Si(s) + 2CO(g) A H° = 689.9 kJ Using the value of A Srxn you calculated from question 10 and/or the value of A G° for the reaction at 25 °C you found in question 11, find the minimum temperature in °C at which this reaction is spontaneous. Assume that A H° and A Sº do not vary with temperature. -271.2 oC 1.912 oC 1639 oC 1912 oC 1614 oC
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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