Answer Q100, 101, 102 One of the isomers of butenedioic acid readilyforms the anhydride when heated92 Butonedioie acid exhibits optical isomerismAliphatic carboxylate ions react with neutra!iron (III) ion to give a yellow precipitate93 Carboxylate fon is a good nucleophile94. The oxygen atom in the H elimin ated whenethanoia acid reach with eihancl comesfrom the acid.In the presence of ethanoic acid, ethanolbehaves like a baseBenzene-1,2-dicarboxylic acid forms the cyclicanhydride by eliminating a water molecule95. Acid anhydrides contain the ether functionalgroup96. Dichlorinatd ethanoic acid is a stronger acidthan themonochlorinated ethanoic acidThe more the number of chlorine atoms onethanoic acid molecule, the stronger the acid.97 Acid chlorides are insoluble in waterAcid chlorides rapidly hydrolysis in waterThe negative inductive effect of the chlorineatom reinforces that of the oxygen atom ofthe carbonylcarbon atom.98. Acid chlorides are the most reactive of thecarbonyl compounds.99 A catalyst is used during the alkalinehydrolysis of esters.Alkaline hydrolysis of esters goes tocompletion while an equilibrium is establishedduring acid hydrolysis.100 The reaction of amides with Br./NaOHincreases the number of carbon atomsThe reaction of amides with Br/NAOH is anexample of a decarboxylation reaction,in the product.101 Benzyamide will undergo the Hofmann'sdegradation reation to phenylamineEthylbenzoate will undergo ammonolysis togive benzamide102 The benzoate lon glves a buff precipitatewith neutral iron (ill) chlorideCarbondioxide is evolved when concentratedHSO, is added to sodium benzoate103. Propanoic acid and propanone bothundergo condensation reaction.Propanoic acid reacts with propan-1-ol toform ester.104. There are three isomers with the molecularformula C,H,O,The compound with molecular formularCHO. exhibits position isomerism.

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100 The reaction of amides with Br./NaOH increases the number of carbon atoms in the product. 101 Benzyamide will undergo the Hofmann's degradation reation to phenylamine 102. The benzoate fon gives a buff precipitate with neutral iron (Ill) chloride

100 The reaction of amides with Br./NaOH increases the number of carbon atoms in the product. 101 Benzyamide will undergo the Hofmann's degradation reation to phenylamine 102. The benzoate fon gives a buff precipitate with neutral iron (Ill) chloride

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Answer Q100, 101, 102

One of the isomers of butenedioic acid readily
forms the anhydride when heated
92 Butonedioie acid exhibits optical isomerism
Aliphatic carboxylate ions react with neutra!
iron (III) ion to give a yellow precipitate
93 Carboxylate fon is a good nucleophile
94. The oxygen atom in the H elimin ated when
ethanoia acid reach with eihancl comes
from the acid.
In the presence of ethanoic acid, ethanol
behaves like a base
Benzene-1,2-dicarboxylic acid forms the cyclic
anhydride by eliminating a water molecule
95. Acid anhydrides contain the ether functional
group
96. Dichlorinatd ethanoic acid is a stronger acid
than themonochlorinated ethanoic acid
The more the number of chlorine atoms on
ethanoic acid molecule, the stronger the acid.
97 Acid chlorides are insoluble in water
Acid chlorides rapidly hydrolysis in water
The negative inductive effect of the chlorine
atom reinforces that of the oxygen atom of
the carbonylcarbon atom.
98. Acid chlorides are the most reactive of the
carbonyl compounds.
99 A catalyst is used during the alkaline
hydrolysis of esters.
Alkaline hydrolysis of esters goes to
completion while an equilibrium is established
during acid hydrolysis.
100 The reaction of amides with Br./NaOH
increases the number of carbon atoms
The reaction of amides with Br/NAOH is an
example of a decarboxylation reaction,
in the product.
101 Benzyamide will undergo the Hofmann's
degradation reation to phenylamine
Ethylbenzoate will undergo ammonolysis to
give benzamide
102 The benzoate lon glves a buff precipitate
with neutral iron (ill) chloride
Carbondioxide is evolved when concentrated
HSO, is added to sodium benzoate
103. Propanoic acid and propanone both
undergo condensation reaction.
Propanoic acid reacts with propan-1-ol to
form ester.
104. There are three isomers with the molecular
formula C,H,O,
The compound with molecular formular
CHO. exhibits position isomerism.

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