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10. [The rate of thermal decomposition for the two azo-based initiators shown below are vastly different when employed for polymerization of styrene at 60 °C. i) Illustrate the mechanism and products of thermal decomposition for each initiator and ii) explain the difference in observed rate constants. (a) (b) yent a apunto = 170 x 106 M.15-1 at 60 °C kd = 9.7 x 106 at 60 °C M.15-1 Kd

10. [The rate of thermal decomposition for the two azo-based initiators shown below are vastly different when employed for polymerization of styrene at 60 °C. i) Illustrate the mechanism and products of thermal decomposition for each initiator and ii) explain the difference in observed rate constants. (a) (b) yent a apunto = 170 x 106 M.15-1 at 60 °C kd = 9.7 x 106 at 60 °C M.15-1 Kd

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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The rate of thermal decomposition for the two azo-based initiators shown below are 10. [. vastly different when employed for polymerization of styrene at 60 °C. i) Illustrate the mechanism and products of thermal decomposition for each initiator and ii) explain the difference in observed rate constants. (b) toont (a) kd = 9.7 x 106 M-15-1 at 60 °C Kd = 170 x 106 M-15-1 at 60 °C
Transcribed Image Text:The rate of thermal decomposition for the two azo-based initiators shown below are 10. [. vastly different when employed for polymerization of styrene at 60 °C. i) Illustrate the mechanism and products of thermal decomposition for each initiator and ii) explain the difference in observed rate constants. (b) toont (a) kd = 9.7 x 106 M-15-1 at 60 °C Kd = 170 x 106 M-15-1 at 60 °C
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