1. To make homemade ice cream, you cool milk and cream by immersing the container in a mixture of ice and a concentrated solution of rock salt (NaCl). a) If you want the water-salt solution to freeze at -12°C, what mass of NaCl must you add to 3.0 kg of ice-water? [Use van't Hoff factor i for NaCl = 1.85. For pure H20: freezing point = 0.00°C; K = 1.86°C-kg-mol', assume the density of water is 1.00 g/mL). b) Briefly explain why the van't Hoff factor for NaCl is greater than one but less than two. c) Briefly explain at the molecular-level the cause of the "depression of the freezing point".

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Chapter1: Chemical Foundations
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! Urgent ! Can you please show all the steps?
1. To make homemade ice cream, you cool milk and cream by immersing the container in a
mixture of ice and a concentrated solution of rock salt (NaCI).
a) If you want the water-salt solution to freeze at-12°C, what mass of NaCl must you add
to 3.0 kg of ice-water? [Use van't Hoff factor i for NaCI = 1.85. For pure H20: freezing
point = 0.00°C; K; = 1.86°C-kg-mol", assume the density of water is 1.00 g/mL).
b) Briefly explain why the van't Hoff factor for NaCl is greater than one but less than two.
c) Briefly explain at the molecular-level the cause of the "depression of the freezing
point".
2. When comparing the same number of moles of non-ionic substances with ionic
substances, why do ionic substances have a greater effect on the freezing and boiling
temperatures of solvents?
3. Calculate the molality, molarity and percent by mass of a solution of ethanol, C2HSOH, and
water in which the mol fraction of ethanol is 0.0820. The density of the solution is 0.978
g/mL.
Transcribed Image Text:! Urgent ! Can you please show all the steps? 1. To make homemade ice cream, you cool milk and cream by immersing the container in a mixture of ice and a concentrated solution of rock salt (NaCI). a) If you want the water-salt solution to freeze at-12°C, what mass of NaCl must you add to 3.0 kg of ice-water? [Use van't Hoff factor i for NaCI = 1.85. For pure H20: freezing point = 0.00°C; K; = 1.86°C-kg-mol", assume the density of water is 1.00 g/mL). b) Briefly explain why the van't Hoff factor for NaCl is greater than one but less than two. c) Briefly explain at the molecular-level the cause of the "depression of the freezing point". 2. When comparing the same number of moles of non-ionic substances with ionic substances, why do ionic substances have a greater effect on the freezing and boiling temperatures of solvents? 3. Calculate the molality, molarity and percent by mass of a solution of ethanol, C2HSOH, and water in which the mol fraction of ethanol is 0.0820. The density of the solution is 0.978 g/mL.
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