1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Aoct) in joules for this d° complex. (Hint: Why is there not a T-S diagram for d° complexes?)
1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Aoct) in joules for this d° complex. (Hint: Why is there not a T-S diagram for d° complexes?)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1. The UV-visible spectrum of an aqueous solution of CuSO₄ (which contains a Cu²⁺ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Δ_oct) in joules for this d⁹ complex. (Hint: Why is there not a T-S diagram for d⁹ complexes?)
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Oct is an energy term, representing the energy gap between the splitted orbitals and have an inverse relation with the wavelength of the incident light used.
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