1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Aoct) in joules for this d° complex. (Hint: Why is there not a T-S diagram for d° complexes?)
1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Aoct) in joules for this d° complex. (Hint: Why is there not a T-S diagram for d° complexes?)
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![1. The UV-visible spectrum of an aqueous solution of CuSO₄ (which contains a Cu²⁺ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Δ_oct) in joules for this d⁹ complex. (Hint: Why is there not a T-S diagram for d⁹ complexes?)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F73f287ec-1f7f-4342-bd76-a85a74415d84%2Fc94e1ac7-4cef-47b3-aca2-2157baae76ee%2F5ihwula_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1. The UV-visible spectrum of an aqueous solution of CuSO₄ (which contains a Cu²⁺ metal center) shows a single peak at 837 nm. Calculate the octahedral field splitting (Δ_oct) in joules for this d⁹ complex. (Hint: Why is there not a T-S diagram for d⁹ complexes?)
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Oct is an energy term, representing the energy gap between the splitted orbitals and have an inverse relation with the wavelength of the incident light used.
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