1. The presence of pi bonds in a molecular structure will always lead to deshielding of the protons and hence an increase in the chemical shift for any adjacent protons to pi bonds true or false? 2. when analyzing mass spectra the largest molecular fragment possible to be created represents the intact unfragmented origonal molecular structure. true or false? 3. electrophilic addition reactions that involve conjugated dienes often produce more than a single product. the kinectic prodyct is generated from the most stable carbocation generated during the mechanistic steps of the reaction. true or false?

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. The presence of pi bonds in a molecular
structure will always lead to deshielding of the
protons and hence an increase in the
chemical shift for any adjacent protons to pi
bonds
true or false?
2. when analyzing mass spectra the largest
molecular fragment possible to be created
represents the intact unfragmented origonal
molecular structure.
true or false?
3. electrophilic addition reactions that involve
conjugated dienes often produce more than a
single product. the kinectic prodyct is
generated from the most stable carbocation
generated during the mechanistic steps of the
reaction.
true or false?
4. All types of molecular bonds are active in
the IR region of the electromagnetic
spectrum.
true or false?
5. The resonance frequency of a proton in H-
NMR spectroscopy is dependent on the local
mahmetic enviroment the proton is found.
These local enviroments produce the various
chemical shifts observed for protons in
various local environments.
True or false?
Transcribed Image Text:1. The presence of pi bonds in a molecular structure will always lead to deshielding of the protons and hence an increase in the chemical shift for any adjacent protons to pi bonds true or false? 2. when analyzing mass spectra the largest molecular fragment possible to be created represents the intact unfragmented origonal molecular structure. true or false? 3. electrophilic addition reactions that involve conjugated dienes often produce more than a single product. the kinectic prodyct is generated from the most stable carbocation generated during the mechanistic steps of the reaction. true or false? 4. All types of molecular bonds are active in the IR region of the electromagnetic spectrum. true or false? 5. The resonance frequency of a proton in H- NMR spectroscopy is dependent on the local mahmetic enviroment the proton is found. These local enviroments produce the various chemical shifts observed for protons in various local environments. True or false?
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