1. The molecule below is a pentose. C/OH H- HO- НО -H НО C/OH
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![1.
The molecule below is a pentose.
C/OH
H-
-ОН
НО
-H
НО
-H
C/OH
The two sugars below are C-4 epimers.
H
H
OI I
НО
H
HC'
H.
H
он
но
H
Но
H
on
CH2OH
C NIH
3
The side chain of glutamine is deprotonated at pH 10.
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- A monosaccharide is formed from a polysaccharide in what kind of reaction? oxidation-reduction reaction anabolic reaction catabolic reaction biosynthetic reactionThe synthetic process by which monomers are covalently linked is (a) hydrolysis (b) isomerization (c) condensation (d) glycosidic linkage (e) ester linkageWhich of the following statements is correct regarding the structures below? CHO CHO H-OH ОН н ОН НО H НО -Н н- ОН CH₂OH CAB All are structures of D-sugars. All are structures of ketohexoses. Only CAR is a monosaccharide. 0 Only CAP is a L-sugar. Н I H CHO -ОН H-OH H-OH н- -ОН CH₂OH CAR H-OH -ОН НО-Н то н- H-OH CH₂OH CAP CH2OH to HO-H НО-н Н 1 - он CH₂OH CAT
- Which of the following statements is correct regarding the structures below? CHO CHO CHO -Н НО H НО н- ОН -Н - ОН CH2OH CAB All are structures of D-sugars. All are structures of ketohexoses. Only CAR is a monosaccharide. O Only CAP is a L-sugar. -ОН -ОН H-OH H-OH H- ОН CH₂OH CAR но-н H-OH н НО т н-он CH₂OH CAP CH₂OH Fo НО-Н H НО-Н H он CH₂OH CAT2. Name the disaccharide (shown at right) formed by glycosidic linkage of D-Glucose and D-Fructose. ● Name this disaccharide: Do you expect this disaccharide to be a reducing sugar? Briefly explain. OH HOCH₂ H CH₂OH I H OH H H HO OH H H O OH H CH₂OH1. Cysteine is an important amino acid that stabilizes the structure of peptides and proteins by the formation of disulfide bond with another cysteine residue. Illustrate the titrimetric profile of cysteine and calculate its isoelectric pH. [Hint: The sulfhydryl group is titratable] 2. The tripeptide Glu-Pro-Arg (EPR) which is a product of Lactobacillus casei fermentation of milk was found to have potent blood pressure lowering properties. Draw the structure of the tripeptide, give its systematic name, show its titration profile, and determine its isoelectric pH.
- Which of the following shorthand names best characterizes the following disaccharide? CHOH OH H. он H. H. OH Glc (a1-4)Gal Gal (a1-4)Glc O Glc (B1-4)Gal Gal (P1-4)Glc1. Below are two isomers of mannose. Classify this sugar based on sugar number. Is this sugar an aldose or a ketose? Indicate which sugar is in the D conformation and which is in the L confirmation. Are these sugars enantiomers or diastereomers? H но-н НО- -Н Н- -ОН Н -ОН CH2OH Н- ІІ НО НО I OH -ОН Н– -Н CH₂OH =1Consider the following carbohydrates: CHO CH2OH но H. OH OH H. OH CH,OH HO HH HO OH OH OH CH-OH CH,OH %3D II Which of these are D-sugars? O All are D-sugars I and II I and IlI Il and III All are L-sugars エ
- Shown here is a monosachharide. How many total forms of this sugar are there? 1 CHO H-2 он н-3 он на I I H4OH + 0 0 0 0 8 2 5CH₂OH 16In 3 sentences, explain this. Discuss the difference between an ⍺-D-glucose and a β-D-glucose. How can the structure of a monosaccharide affect its bioactivity?1. The figure below shows the Fischer projection of an L-aldohexose. T or F O. НО H- Но H- Но- ČH2OH Naturally occurring saturated long-chain fatty acids are usually in trans- configuration. 2. T or F 3. N-acetylglucosamine is commonly found in glycosaminoglycans. T or F 4. The isoelectric point of isoleucine is lower than that of histidine. T or F 5.. At pH 7, all amino acids stop migrating in isoelectric focusing. T or F 6. The following amino acid is a L-valine. T or F СООН H-NH2 CH-CH3 CH3 7. Salting out is a process to remove salts from proteins. T or F 8. There are five carbons in a pyranose ring. T or F 9. Hydrophobic interaction can be found in protein and DNA. T or F RNA is a polymer consisting of nucleosides joined together by phosphodiester bonds. 10. T or F 11. There are 3.6 base pairs in one turn of DNA helix. T or F
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