1. The following liquid-phase reactions were carried out in a CSTR at 325 K: 3A B+C, TIA KIACA, KIA 7.0 min¹ 2C+ A→3D, 12Dk2DC²CA, k2D = 3.0 dm%/(mol²-min) 4D+3C3E, T3E=K3ECDCC, K3=2.0 dm³/(mol-min) The concentrations measured inside the reactor were CA=0.10, CB=0.93, C₂-0.51, and CD- 0.049 all in mol/dm³. (a) What are the values of T1A, 2A, and T3A? (b) What are the values of TIB, 2B, and T³B? (c) What are the values of ric, r2c, and ric? (d) What are the values of riD, 2D, and rp? (e) What are the values of TIE, TE, and TJE? (f) What are the net rates of formation of A, B, C, D, and E? (g) The entering volumetric flow rate is 100 dm³/min and the entering concentration of A is 3 M. What is the CSTR reactor volume? (h) What are the exit molar flow rate of component E from the above CSTR. (i) PFR. Now assume the reactions take place in the gas phase. Use the preceding data to plot the molar flow rate's selectivity and p as a function of PFR volume up to 400 dm³. The pressure- drop parameter is 0.001 dm³, the total concentration entering the reactor is 0.2 mol/dm³, and vo= 100 dm'/min. What are Sp/g and Sc/D? Plot the conversion and pressure drop as a function of PFR volume.
1. The following liquid-phase reactions were carried out in a CSTR at 325 K: 3A B+C, TIA KIACA, KIA 7.0 min¹ 2C+ A→3D, 12Dk2DC²CA, k2D = 3.0 dm%/(mol²-min) 4D+3C3E, T3E=K3ECDCC, K3=2.0 dm³/(mol-min) The concentrations measured inside the reactor were CA=0.10, CB=0.93, C₂-0.51, and CD- 0.049 all in mol/dm³. (a) What are the values of T1A, 2A, and T3A? (b) What are the values of TIB, 2B, and T³B? (c) What are the values of ric, r2c, and ric? (d) What are the values of riD, 2D, and rp? (e) What are the values of TIE, TE, and TJE? (f) What are the net rates of formation of A, B, C, D, and E? (g) The entering volumetric flow rate is 100 dm³/min and the entering concentration of A is 3 M. What is the CSTR reactor volume? (h) What are the exit molar flow rate of component E from the above CSTR. (i) PFR. Now assume the reactions take place in the gas phase. Use the preceding data to plot the molar flow rate's selectivity and p as a function of PFR volume up to 400 dm³. The pressure- drop parameter is 0.001 dm³, the total concentration entering the reactor is 0.2 mol/dm³, and vo= 100 dm'/min. What are Sp/g and Sc/D? Plot the conversion and pressure drop as a function of PFR volume.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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