1. Sketch the relative energy levels for the d- orbitals below each of the geometries (a - c) and using a common oxidation state for Mn metal fill in the orbitals with available d-electrons. Metal = Ox State #d-electrons = a) Octahedral b) Square Planar c) Tetrahedral d) Briefly explain the term "high spin" and "low spin" and identify if those terms can be used to describe Mn metal in the oxidation state used for parts a) Octahedral b) Square Planar c) Tetrahedral? = +

Q: What is the oxidation state and coordination number (C.N.) of the metal atom in the following…

A: Given the complex is as follows; [Mn(acac)2(SCN)(OH)]

Q: Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on…

A:

Q: Name these coordination compounds. formula MoBs,(H,0).] Br

A:

Q: Explain in detail π backbonding using the molecular orbitals of CO and a d-transition metal. How…

A:

Q: 8. when the d orbital of the central Metal ion are supply in a square planar Crystal field, which…

A:

Q: 13) Consider [MnX6]4, where the ligands, X are especially strong-field ligands and are monodentate.…

A:

Q: 1. Predict the crystal field splitting diagrams for the following coordination compounds. Provide a…

A:

Q: Draw crystal - field energy level diagrams for the d electrons for the following complex ions. Label…

A: For high spin either ligand should be strong or 3 d metals must have greater than +3 oxidation date…

Q: what is the electron configuration of Mn in [MnO4]1+ b, what is the magnetic moment of Mn in [MnO4]…

A: The given compound is made up of one manganese and four oxygen atoms.Oxidation number of  oxygen (O)…

Q: 8. Consider the number of d-electrons for Mn³+ and the ligand strength of the ligands, H₂O en, and…

A: l

Q: 12. Draw the energy diagram of a high-spin and a low-spin complex of chromium(III) as central ion…

A: High spin and low spin complexesThe complex can be characterised as high spin or low spin based on…

Q: 5. a) Draw the structures of the following complexes: i) Dichlorobis(ethylenediamine)platinum(IV)…

A: We have to draw the structure of the given coordination compounds, from the given names.

Q: c) Using energy as the vertical axis, in the space below make a sketch that includes each of the…

A:

Q: 12) Consider [CuCl4] Cl2. a) What is the oxidation state of the metal? b) What is the coordination…

A: Coordination number(CN): CN of metal ion is defined as the number of ligand donar atoms to which the…

Q: None

A: Coordination Numbers[CuCl4]2-: Coordination number is 4 (four chloride ions).[Ag(CN)2]−:…

Q: 34.. As the value of the crystal field splitting, Ao, increases from one complex ion to another, a)…

A:

Q: For the following crystal field splitting diagrams, identify: i. The crystal field geometry Whether…

A: We only answer 1 question from multiple questions with sub-parts. Please resubmit other questions…

Q: Construct an MO diagram for staggered ferrocene 1. What is the oxidation state of Fe in ferrocene?2.…

A: 1. The oxidation state of Fe in ferrocene is +2.2. There are 6 d-electrons counted on Fe in…

Q: Using the electronic configuration of the transition metals, briefly (less than 60 words) explain…

A: Electronic configuration of an element is used to distribute the electrons in the given orbitals.…

Q: 15. Earth abundant Ni compounds with appropriate ligands have been reported to catalyze C- C bond…

A:

Q: Please draw the metal coordination structure of a carbonic anhydrase enzyme. Also, please clearly…

A: Carbonic anhydrase is an enzyme used to catalyze certain chemical reaction.  The chemical reaction…

Q: For the octahedral crystal field diagram discussed in lecture, draw two energy level diagrams of the…

A: The formation of hard spin complex and low spin complex depends upon the ligand attached to central…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.