1. Real-life heat Capacity is temperature dependent. Consider the formation of water vapor H2(g)+( ½)O2(g) → H20(g) The heat capacities Cp(T) for each of the reactants and the product is given by Cp=a+bT+CT 2 where the constants a, b and c depend on the substance. The above equation is valid from 298 K to 2,000 K. a. The units of a, b and c are .? b. Calculate AH given (298 K)=-60kCal. Express your answers in terms of a, b, c for the reactants and products (aH2, bH2 --) (Answers choices for part b) AH (T) = -60kCal AH (T) = -60kCal + (aH,0 – an, – ļa0,) (T – 298K) + 4 (b,0 – bu, – įbo.) (T² – 298° K²) – (cH,0 – CH, – ¿co,) († - AH (T) = (an,0 – a, – ža0,) (T – 298K) + (bn,0 – bu, – įbo,) (Tª – 298° K²) – (c1,0 – en, – įco,) († - *K) 208K O AH (T) = -60kCal – (an,0 – an, – ža0,) (T – 298K) – † (bH,0 – bu, – įbo,) (Tª – 298° K²) + (cH,0 – cH, – ļco.) († - )
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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