1. Predict the major product. a. b. C. CHO NH₂ + + 1. EtOH, HCI 2. NaOH, H₂O NH2 NaBH3CN, HCI H N 1, excess CH31 2, Ag2O, H2O, heat (ONE carbon more than reactant) d. S f. Ο Ο S 1. KOH, H₂O N 2. Benzoic acid 3. Dibal-H; then work-up KOH, H₂O N then 6 g. 1, LDA, -78°C, then Etl 2, LDA, -78°C, then Mel h. 1, NaH, 25°C, then Etl 2, NaH, 25°C, then Mel

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. Predict the major product.
a.
b.
C.
CHO
NH₂
+
+
1. EtOH, HCI
2. NaOH, H₂O
NH2
NaBH3CN, HCI
H
N
1, excess CH31
2, Ag2O, H2O, heat
(ONE carbon more than reactant)
d.
S
f.
Ο Ο
S
1. KOH, H₂O
N
2. Benzoic acid
3. Dibal-H; then work-up
KOH, H₂O
N
then
6
g.
1, LDA, -78°C, then Etl
2, LDA, -78°C, then Mel
h.
1, NaH, 25°C, then Etl
2, NaH, 25°C, then Mel
Transcribed Image Text:1. Predict the major product. a. b. C. CHO NH₂ + + 1. EtOH, HCI 2. NaOH, H₂O NH2 NaBH3CN, HCI H N 1, excess CH31 2, Ag2O, H2O, heat (ONE carbon more than reactant) d. S f. Ο Ο S 1. KOH, H₂O N 2. Benzoic acid 3. Dibal-H; then work-up KOH, H₂O N then 6 g. 1, LDA, -78°C, then Etl 2, LDA, -78°C, then Mel h. 1, NaH, 25°C, then Etl 2, NaH, 25°C, then Mel
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