1. Occasionally, a crossed Cannizzaro reaction is carried out to reduce benzaldehyde derivatives to the corresponding benzyl alcohol, utilizing formaldehyde as the reducing agent. i) Please show the mechanism by which this occurs. ii) Why is this method'effecti ve? That is, why are the principal products benzyl alcohol and formic acid and not benzoic acid and methanol?
1. Occasionally, a crossed Cannizzaro reaction is carried out to reduce benzaldehyde derivatives to the corresponding benzyl alcohol, utilizing formaldehyde as the reducing agent. i) Please show the mechanism by which this occurs. ii) Why is this method'effecti ve? That is, why are the principal products benzyl alcohol and formic acid and not benzoic acid and methanol?
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter16: Aldehydes And Ketones
Section: Chapter Questions
Problem 16.26P: Wittig reactions with the following -chloroethers can be used for the synthesis of aldehydes and...
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