1. Melted methane was ignited and used to heat water in a thin metal container. After a short period of time, the methane was extinguished and final measurements were made. Mass of methane before burning Mass of methane after burning Mass of water in container Initial temperature of water Final temperature of water = 7.52 g = 7.20 g = 140.0 g = 10.0°C = 32.0°C a) Using this data, calculate the heat of combustion of methane in kJ/mol. Assume that all the heat from the methane was absorbed by the water b) Write the thermochemical equation for the complete combustion of methane.

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1. Melted methane was ignited and used to heat water in a thin metal container. After a short period of time, the
methane was extinguished and final measurements were made.
Mass of methane before burning
Mass of methane after burning
Mass of water in container
Initial temperature of water
Final temperature of water
= 7.52 g
= 7.20 g
= 140.0 g
= 10.0°C
= 32.0°C
a) Using this data, calculate the heat of combustion of methane in kJ/mol. Assume that all the heat from the
methane was absorbed by the water
b) Write the thermochemical equation for the complete combustion of methane.
Transcribed Image Text:1. Melted methane was ignited and used to heat water in a thin metal container. After a short period of time, the methane was extinguished and final measurements were made. Mass of methane before burning Mass of methane after burning Mass of water in container Initial temperature of water Final temperature of water = 7.52 g = 7.20 g = 140.0 g = 10.0°C = 32.0°C a) Using this data, calculate the heat of combustion of methane in kJ/mol. Assume that all the heat from the methane was absorbed by the water b) Write the thermochemical equation for the complete combustion of methane.
Selected Standard Molar Enthalpies of Formation
AH₁
AH;
AH₁
Substance (kJ/mol) Substance (kJ/mol) Substance (kJ/mol)
Al₂O3(s)
-1675.7 HBr(g)
CaCO3(s)
-1207,6 HCl(g)
CaCl₂(s)
Ca(OH)₂(s)
CCL₂(E)
CCL4(8)
CHCI ()
CH₂(g)
C₂H₂(g)
C₂H₁(g)
C₂H₂(g)
CzHs(g)
CH()
CH₂OH(E)
C₂H₂OH()
CO(g)
CO₂(g)
COCI₂(g)
+49.1 Fe₂O₂(8)
-239.2 Fe,O4(s)
-277.6 FeCl₂(s)
CH3COOH(E) –484.3 FeCls(s)
-110.5 FeS (8)
CS₂(e)
CS₂(g)
CrCla(g)
Cu(NO₂)₂ (8)
-795.4 HF(g)
-985.2 HCN(g).
-128.2 H₂O(E)
-95.7 H₂O(g)
CuO(s)
CuCl(s)
CuCl₂(s)
-134.1 H₂O₂(e)
-74.6 HNO (0)
+227.4 H₂PO4(s)
+52.4 H₂S(g)
-84.0 H₂SO4(e)
-103.8 FeO(s)
–36.3|NH(8)
-92.3 N₂H4(e)
-273.3 NH Cl(s)
+135.1 NH₂NO(s)
-285.8 NO(g)
-393.5 PbCl₂(s)
-219.1 MgCl₂(s)
+89.0 MgO(s)
+116.7 Mg(OH)2(s)
-556.5 HgS(s)
-241.8 NO₂(g)
-187.8 N₂O(g)
-174.1 N₂O(g)
1284.4 PH,(g)
-20.6 PCl₂(g)
814.0 P,O,(s)
-272.0 P4O₁0(s)
-824.2 KBr(s)
-1118.4 KCl(s)
-341.8 KCIO,(s)
-399.5 KOH(s)
-178.2 AgaCO₂ (s)
-359.4 AgCl(s)
-641.3 AgNO,(s)
-601.6 Ag S(s)
-924.5 SFB(g)
-58.2 SO₂(g)
-302.9 NaCl(s)
-411.2 SO₂(g)
-157.3 NaOH(s)
-425.6 SnCl₂(s)
-137.2 Na₂CO3(s)-1130.7 SnCl4(e)
-220.1
-45.9
+50.6
-314.4
-365.6
+91.3
+33.2
+81.6
+11.1
+5.4
-287.0
-2144.3
-2984.0
-393.8
-436.5
-397.7
-424.6
-505.8
-127.0
-124.4
-32.6
-1220.5
-296.8
-395.7
-325.1
-511.3
Note: The enthalpy of formation of an element in its standard state is
defined as zero.
Transcribed Image Text:Selected Standard Molar Enthalpies of Formation AH₁ AH; AH₁ Substance (kJ/mol) Substance (kJ/mol) Substance (kJ/mol) Al₂O3(s) -1675.7 HBr(g) CaCO3(s) -1207,6 HCl(g) CaCl₂(s) Ca(OH)₂(s) CCL₂(E) CCL4(8) CHCI () CH₂(g) C₂H₂(g) C₂H₁(g) C₂H₂(g) CzHs(g) CH() CH₂OH(E) C₂H₂OH() CO(g) CO₂(g) COCI₂(g) +49.1 Fe₂O₂(8) -239.2 Fe,O4(s) -277.6 FeCl₂(s) CH3COOH(E) –484.3 FeCls(s) -110.5 FeS (8) CS₂(e) CS₂(g) CrCla(g) Cu(NO₂)₂ (8) -795.4 HF(g) -985.2 HCN(g). -128.2 H₂O(E) -95.7 H₂O(g) CuO(s) CuCl(s) CuCl₂(s) -134.1 H₂O₂(e) -74.6 HNO (0) +227.4 H₂PO4(s) +52.4 H₂S(g) -84.0 H₂SO4(e) -103.8 FeO(s) –36.3|NH(8) -92.3 N₂H4(e) -273.3 NH Cl(s) +135.1 NH₂NO(s) -285.8 NO(g) -393.5 PbCl₂(s) -219.1 MgCl₂(s) +89.0 MgO(s) +116.7 Mg(OH)2(s) -556.5 HgS(s) -241.8 NO₂(g) -187.8 N₂O(g) -174.1 N₂O(g) 1284.4 PH,(g) -20.6 PCl₂(g) 814.0 P,O,(s) -272.0 P4O₁0(s) -824.2 KBr(s) -1118.4 KCl(s) -341.8 KCIO,(s) -399.5 KOH(s) -178.2 AgaCO₂ (s) -359.4 AgCl(s) -641.3 AgNO,(s) -601.6 Ag S(s) -924.5 SFB(g) -58.2 SO₂(g) -302.9 NaCl(s) -411.2 SO₂(g) -157.3 NaOH(s) -425.6 SnCl₂(s) -137.2 Na₂CO3(s)-1130.7 SnCl4(e) -220.1 -45.9 +50.6 -314.4 -365.6 +91.3 +33.2 +81.6 +11.1 +5.4 -287.0 -2144.3 -2984.0 -393.8 -436.5 -397.7 -424.6 -505.8 -127.0 -124.4 -32.6 -1220.5 -296.8 -395.7 -325.1 -511.3 Note: The enthalpy of formation of an element in its standard state is defined as zero.
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