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1. Liquid extraction is an operation used to separate the components of a liquid mixture of two or more species. In the simplest case, the mixture contains two components: a solute (A) and a liquid solvent (B). The mixture is contacted in an agitated vessel with a second liquid solvent (C) that has two key properties: A dissolves in it, and B is immiscible or nearly immiscible with it. (For example, B may be water, Ca hydrocarbon oil, and A a species soluble in both water and oil.) Some of the A transfers from B to C, and then the B-rich phase (the raffinate) and the C-rich phase (the extract) separate from each other in a settling tank. If the raffinate is then contacted with fresh C in another stage, more A will be transferred from it. This process can be repeated until essentially all of the A has been extracted from the B. Shown below is a flowchart of a process in which acetic acid (A) is extracted from a mixture of acetic acid and water (B) into 1-hexanol (C), a liquid immiscible with water. mcdg C,H13OH/min) me(g/min) 0.096 g CH,COOH/g 0.904 g CH13OH/g 400 g/min mR(g/min) 0.115 g CH,COOH/g 0.885 g H,O/g 0.005 g CH3COOH/g 0.995 g H2O/g

1. Liquid extraction is an operation used to separate the components of a liquid mixture of two or more species. In the simplest case, the mixture contains two components: a solute (A) and a liquid solvent (B). The mixture is contacted in an agitated vessel with a second liquid solvent (C) that has two key properties: A dissolves in it, and B is immiscible or nearly immiscible with it. (For example, B may be water, Ca hydrocarbon oil, and A a species soluble in both water and oil.) Some of the A transfers from B to C, and then the B-rich phase (the raffinate) and the C-rich phase (the extract) separate from each other in a settling tank. If the raffinate is then contacted with fresh C in another stage, more A will be transferred from it. This process can be repeated until essentially all of the A has been extracted from the B. Shown below is a flowchart of a process in which acetic acid (A) is extracted from a mixture of acetic acid and water (B) into 1-hexanol (C), a liquid immiscible with water. mcdg C,H13OH/min) me(g/min) 0.096 g CH,COOH/g 0.904 g CH13OH/g 400 g/min mR(g/min) 0.115 g CH,COOH/g 0.885 g H,O/g 0.005 g CH3COOH/g 0.995 g H2O/g

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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1. Liquid extraction is an operation used to separate the components of a liquid mixture of two or more species. In the simplest case, the mixture contains two components: a solute (A) and a liquid solvent (B). The mixture is contacted in an agitated vessel with a second liquid solvent (C) that has two key properties: A dissolves in it, and B is immiscible or nearly immiscible with it. (For example, B may be water, Ca hydrocarbon oil, and A a species soluble in both water and oil.) Some of the A transfers from B to C, and then the B-rich phase (the raffinate) and the C-rich phase (the extract) separate from each other in a settling tank. If the raffinate is then contacted with fresh C in another stage, more A will be transferred from it. This process can be repeated until essentially all of the A has been extracted from the B. Shown below is a flowchart of a process in which acetic acid (A) is extracted from a mixture of acetic acid and water (B) into 1-hexanol (C), a liquid immiscible with water. mdg C,H13OH/min) mg(g/min) 0.096 g CH,COOH/g 0.904 g C,H13OH/g 400 g/min mR(g/min) 0.115 g CH,COOH/g 0.885 g H,O/g 0.005 g CH;COOH/g 0.995 g H2O/g
Transcribed Image Text:1. Liquid extraction is an operation used to separate the components of a liquid mixture of two or more species. In the simplest case, the mixture contains two components: a solute (A) and a liquid solvent (B). The mixture is contacted in an agitated vessel with a second liquid solvent (C) that has two key properties: A dissolves in it, and B is immiscible or nearly immiscible with it. (For example, B may be water, Ca hydrocarbon oil, and A a species soluble in both water and oil.) Some of the A transfers from B to C, and then the B-rich phase (the raffinate) and the C-rich phase (the extract) separate from each other in a settling tank. If the raffinate is then contacted with fresh C in another stage, more A will be transferred from it. This process can be repeated until essentially all of the A has been extracted from the B. Shown below is a flowchart of a process in which acetic acid (A) is extracted from a mixture of acetic acid and water (B) into 1-hexanol (C), a liquid immiscible with water. mdg C,H13OH/min) mg(g/min) 0.096 g CH,COOH/g 0.904 g C,H13OH/g 400 g/min mR(g/min) 0.115 g CH,COOH/g 0.885 g H,O/g 0.005 g CH;COOH/g 0.995 g H2O/g
a. What is the maximum number of independent material balances that can be written for this process? b. Calculate m., mɛ, and mr using the given mixture feed rate as a basis and writing balances in an order such that you never have an equation that involves more than one unknown variable. c. Calculate the difference between the amount of acetic acid in the feed mixture and that in the 0.5% mixture, and show that it equals the amount that leaves in the 9.6% mixture. d. Acetic acid is relatively difficult to separate completely from water by distillation and relatively easy to separate from hexanol by distillation. Sketch a flowchart of a two-unit process that might be used to recover nearly pure acetic acid from an acetic acid-water mixture.
Transcribed Image Text:a. What is the maximum number of independent material balances that can be written for this process? b. Calculate m., mɛ, and mr using the given mixture feed rate as a basis and writing balances in an order such that you never have an equation that involves more than one unknown variable. c. Calculate the difference between the amount of acetic acid in the feed mixture and that in the 0.5% mixture, and show that it equals the amount that leaves in the 9.6% mixture. d. Acetic acid is relatively difficult to separate completely from water by distillation and relatively easy to separate from hexanol by distillation. Sketch a flowchart of a two-unit process that might be used to recover nearly pure acetic acid from an acetic acid-water mixture.
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