1. In each of the equations below, label the acids, bases and their conjugates. HCOOH + H2O ↔ HCOO- + H3O+                                 HPO42- + H2O ↔ H2PO4- + OH-                                 NH3 + H2O ↔ OH- + NH4+

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Chapter1: Chemical Foundations
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1. In each of the equations below, label the acids, bases and their conjugates.

HCOOH + H2O HCOO- + H3O+
                             
 
HPO42- + H2O H2PO4- + OH-
                             
 
NH3 + H2O OH- + NH4+
                             

2.

Decide which of the following statements are True and which are False about equilibrium systems:


    A large value of K means the equilibrium position lies far to the left.

    For a reaction with K >> 1, the rate of the forward reaction is greater than the rate of the reverse reaction at equilibrium.

    For the following reaction: H2(g) + F2(g) ⇌ 2HF(g) the values of K and Kp are the same.

    For the following reaction: CaCO3(s) ⇌ CaO(s) + CO2(g) the [CaCO3] appears in the denominator of the equilibrium expression.

    The value of K at constant temperature does not depend on the amounts of reactants and products that are mixed together initially.

3.

Given the following equilibrium constants at 427°C:

 

O2(g) + 4Na(l)  2Na2O(s)     K1 = 2.50×1049

 

O2(g) + 2Na(l)  2NaO(g)     K2 = 2.50×109

 

O2(g) + 2Na(l)  Na2O2(s)     K3 = 2.00×1028

 

O2(g) + Na(l)  NaO2(s)     K4 = 3.33×1013

What would be the value of the equilibrium constant for each of the following reactions, at 427°C?

 

 

Na2O2(s) + O2(g)  2NaO2(s)

 

  Incorrect. Tries 1/99 Previous Tries

 

4NaO2(s)  2Na2O(s) + 3O2(g)

4. Given:

Si(s) + 2H2(g)  SiH4(g) K = 7.76×106

 

C(graphite) + SiH4(g)  CH4(g) + Si(s) K = 1.02×102

What is the equilibrium constant for the following reaction?

 

C(graphite) + 2H2(g)  CH4(g)


5.

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