1. Identify the following reactions by type and predict the products (any 4): (i) (ii) (iii) (iv) (v) Pt(O,) (PPh;)2 + 2CS2 RhH(CO)(PPh;)3 +CF. [C,H,Mn (CO)3]* +H CH;Mn(CO), + C,H;NH, IrCI(PMe;), + HCO

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Chapter1: Chemical Foundations
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( do no 1 with explanation any 4 rxn)
1. Identify the following reactions by type and predict the products (any 4):
(i)
(ii)
(iii)
(iv)
(v)
2. "Selectivity of Wilkinson's catalyst is largely a consequence of the bulky triphenylphosphine ligands, the
Pt(O2) (PPH3)2 + 2CS2
RhH(CO)(PPH3)3 +CF.
[C,H,Mn (CO);]* + H
CH;Mn(CO), + C,H&NH2
IrCI(PMe,); + HCO
selectivity can be fine-tunned by using phosphines having different cone angles than PPh;" Explain
Transcribed Image Text:1. Identify the following reactions by type and predict the products (any 4): (i) (ii) (iii) (iv) (v) 2. "Selectivity of Wilkinson's catalyst is largely a consequence of the bulky triphenylphosphine ligands, the Pt(O2) (PPH3)2 + 2CS2 RhH(CO)(PPH3)3 +CF. [C,H,Mn (CO);]* + H CH;Mn(CO), + C,H&NH2 IrCI(PMe,); + HCO selectivity can be fine-tunned by using phosphines having different cone angles than PPh;" Explain
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