Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please answer 1-3 thank you
![Diels-Alder Reaction
1. Give the structures of the products obtained when the following are heated:
Ph
Me
OMe
b.
a.
+
O,N
Ph
C.
NC
CN
d.
2 Which compounds would you heat together in order to synthesize each of the
following?
CHO
3. The 1,4-diphenyl-1,3-butadiene that you used is the (E,E)-isomer. The phenyl
groups in your product are cis with respect to each other. USING
STEREOCHEMICAL FORMULAS, explain why the (E,E)- diene gives an adduct
in which the phenyl groups are cis. (HINT: Remember that there is free rotation
around single bonds, and study the discussion of the stereochemistry of the
Diels-Alder reaction in your text.)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2acd1a8d-4262-4744-b59c-97c60e218c22%2F4cea9abe-26cf-4d42-9d36-88e71fd801bf%2F1o9olo6_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Diels-Alder Reaction
1. Give the structures of the products obtained when the following are heated:
Ph
Me
OMe
b.
a.
+
O,N
Ph
C.
NC
CN
d.
2 Which compounds would you heat together in order to synthesize each of the
following?
CHO
3. The 1,4-diphenyl-1,3-butadiene that you used is the (E,E)-isomer. The phenyl
groups in your product are cis with respect to each other. USING
STEREOCHEMICAL FORMULAS, explain why the (E,E)- diene gives an adduct
in which the phenyl groups are cis. (HINT: Remember that there is free rotation
around single bonds, and study the discussion of the stereochemistry of the
Diels-Alder reaction in your text.)
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