1. For each of the following statements, indicate whether they are true of false. ⚫a characteristic feature of the carbonyl group is that it has partial positive charge on the carbon atom and partial negative charge on the oxygen atom - this is what imbues it with the ability to behave as an electrophile on the carbon atom. ⚫all carbonyl groups are equally electrophilic. ⚫the groups attached to a carbonyl group have a tiny influence on how electrophilic it is. • protonation of a carbonyl group makes it more electrophilic. • the previous statement, while true, is a gross understatement (tantamount to saying that the Atlantic Ocean is larger than Mundy Pond). • an alkoxide (RO) is more nucleophilic than its conjugate acid (ROH). • the previous statement, while true, is a gross understatement (tantamount to saying that the Canada is larger than Vatican City).

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter23: Amines
Section: Chapter Questions
Problem 23.67P
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1. For each of the following statements, indicate whether they are true of false.
⚫a characteristic feature of the carbonyl group is that it has partial positive charge on the carbon
atom and partial negative charge on the oxygen atom - this is what imbues it with the ability to
behave as an electrophile on the carbon atom.
⚫all carbonyl groups are equally electrophilic.
⚫the groups attached to a carbonyl group have a tiny influence on how electrophilic it is.
• protonation of a carbonyl group makes it more electrophilic.
• the previous statement, while true, is a gross understatement (tantamount to saying that the
Atlantic Ocean is larger than Mundy Pond).
• an alkoxide (RO) is more nucleophilic than its conjugate acid (ROH).
• the previous statement, while true, is a gross understatement (tantamount to saying that the
Canada is larger than Vatican City).
Transcribed Image Text:1. For each of the following statements, indicate whether they are true of false. ⚫a characteristic feature of the carbonyl group is that it has partial positive charge on the carbon atom and partial negative charge on the oxygen atom - this is what imbues it with the ability to behave as an electrophile on the carbon atom. ⚫all carbonyl groups are equally electrophilic. ⚫the groups attached to a carbonyl group have a tiny influence on how electrophilic it is. • protonation of a carbonyl group makes it more electrophilic. • the previous statement, while true, is a gross understatement (tantamount to saying that the Atlantic Ocean is larger than Mundy Pond). • an alkoxide (RO) is more nucleophilic than its conjugate acid (ROH). • the previous statement, while true, is a gross understatement (tantamount to saying that the Canada is larger than Vatican City).
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