Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Organic Chemistry Reactions
**Objective:**
Draw the organic products formed in each reaction.
**Reactions and Explanations:**
#### a) Reaction with Tert-Butoxide Ion (\((CH_3)_3CO^-\))
- **Starting Material:** 1-Bromo-3-methylbutane
- **Reagent:** \((CH_3)_3CO^-\)
- **Description:**
- The bromine atom (Br) in the molecule acts as the leaving group.
- The tert-butoxide ion \((CH_3)_3CO^-\) is a strong base, typically resulting in an E2 elimination reaction.
- The product typically formed would involve the elimination of HBr, producing an alkene.
#### b) Reaction with Tert-Butoxide Ion (\((CH_3)_3CO^-\))
- **Starting Material:** 1-Bromo-1-methylcyclohexane
- **Reagent:** \((CH_3)_3CO^-\)
- **Description:**
- The bromine atom is the leaving group.
- The strong base \((CH_3)_3CO^-\) causes an E2 elimination reaction.
- The result is the formation of an alkene through the elimination of HBr.
#### c) Reaction with Water (H₂O)
- **Starting Material:** 1-Bromo-2-methylcyclohexane
- **Reagent:** \(H_2O\)
- **Description:**
- Water acts as a weak nucleophile.
- The reaction mechanism typically involves SN1 since it proceeds through a carbocation intermediate.
- The product formed would be an alcohol after substitution of the bromine atom.
#### d) Reaction with Sodium Methoxide (NaOCH₃)
- **Starting Material:** 1-Bromo-2-phenylpropane
- **Reagent:** NaOCH₃
- **Description:**
- The bromine atom acts as the leaving group.
- Sodium methoxide (NaOCH₃) is a strong base and nucleophile.
- This reaction can proceed either via E2 mechanism (leading to elimination product) or SN2 mechanism (leading to substitution product).
**Graphs/Diagrams Explanation:**
- Four reaction schemes are illustrated where each shows the structural formula of the starting material and the reagent involved.
- In each scheme](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F44572439-aee9-40a4-8ec4-b1e043de89f6%2F0a23bafe-d67b-498c-a2d1-81534b7d5fcc%2Fbfhqo0h_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Organic Chemistry Reactions
**Objective:**
Draw the organic products formed in each reaction.
**Reactions and Explanations:**
#### a) Reaction with Tert-Butoxide Ion (\((CH_3)_3CO^-\))
- **Starting Material:** 1-Bromo-3-methylbutane
- **Reagent:** \((CH_3)_3CO^-\)
- **Description:**
- The bromine atom (Br) in the molecule acts as the leaving group.
- The tert-butoxide ion \((CH_3)_3CO^-\) is a strong base, typically resulting in an E2 elimination reaction.
- The product typically formed would involve the elimination of HBr, producing an alkene.
#### b) Reaction with Tert-Butoxide Ion (\((CH_3)_3CO^-\))
- **Starting Material:** 1-Bromo-1-methylcyclohexane
- **Reagent:** \((CH_3)_3CO^-\)
- **Description:**
- The bromine atom is the leaving group.
- The strong base \((CH_3)_3CO^-\) causes an E2 elimination reaction.
- The result is the formation of an alkene through the elimination of HBr.
#### c) Reaction with Water (H₂O)
- **Starting Material:** 1-Bromo-2-methylcyclohexane
- **Reagent:** \(H_2O\)
- **Description:**
- Water acts as a weak nucleophile.
- The reaction mechanism typically involves SN1 since it proceeds through a carbocation intermediate.
- The product formed would be an alcohol after substitution of the bromine atom.
#### d) Reaction with Sodium Methoxide (NaOCH₃)
- **Starting Material:** 1-Bromo-2-phenylpropane
- **Reagent:** NaOCH₃
- **Description:**
- The bromine atom acts as the leaving group.
- Sodium methoxide (NaOCH₃) is a strong base and nucleophile.
- This reaction can proceed either via E2 mechanism (leading to elimination product) or SN2 mechanism (leading to substitution product).
**Graphs/Diagrams Explanation:**
- Four reaction schemes are illustrated where each shows the structural formula of the starting material and the reagent involved.
- In each scheme
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