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![1. Calculate the number of elements of unsaturation implied by the molecular formula:
a. CaH12
b. CSHSNO2
c. CeH3NCIBr
d. C4HaO
2 Civo the ILI RAC naoog of th
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- 8. Draw a non-cyclic isomer of C3H6N2 in which the atom connectivity is N-C-C–C-N, and the middle C–C–C unit does NOT have a bond angle of 180°.1. What is resonance contributor in which one or more atoms bears a formal change and the most stable resonance form? 2.what is the process of distributing electron pairs in a molecule? 3. Are organic molecules which are less sterically hindered more attractive than those which are more sterically hindered?4. The full structural formula of three organic compounds, P, Q and R, are shown below. H H HHH H HHHH H- C-C- H H C C-C = C- H H C C C C-H H H H H H. a. State one similarity between P, Q and R in terms of their molecular formula. b. Name the homologous series that compounds P, Q and R belong to. c. State one similarity between Q and R in terms of chemical bonding. d. Which of these compounds are isomers? Explain your answer.
- 42. Which of the following is not a functional isomer? A. CH,OH H НА a H Me B. C. D. Me H -ОН OH (A) O CH, CH, 0 CH3 OCH, (B) 43. Which of the following has a zero dipole moment? Choose the best answer. CI OH O CH, CH, (B) O H 1-1 C CI 44. Which of the following exhibits geometric isomerism? OH (C) (C) OH (D) 45. Which would be the most stable conformation of trans-1-ethyl-3-methylcylcohexane? (D) OH4. Assign R and S nomenclature to the chiral carbon atoms CI H. OCH3 а. с. b. HOH2C" `COOH CI1. What type of reaction that all organic compounds undergo? 2. What is the total bond order of sulfur in CH3SCH3? 3. Explain the meaning in organic formulas of a pair of parentheses with no subscript behind it, such as in CH3CH2CH(CH3)C3H7
- Draw a skeletal structure for the molecules in parts (a) and (b), and a condensed structure for the molecules in parts (c) and (d). a. CH3O(CH2)2COCH = C(CH3)2Which structure is correct? O SBr2 .S. Br Br: O N2 :NEN: OPH4 H. O CH3NH3 H. N H.4. what is the relationship between these two compounds? H,C. CH3 CH3 CH2 CH3 H;C, ĆH CH CH3 CH CH CH3 C H2 H3C H2 H, H2 H2 А
- H. H. Н H-C-C-0-Ċ-H | H H Н condensed structure: || CH3-CH2-O-CH31. How many carbon and hydrogen atoms are in the following molecule? Draw in all the lone pairs to complete the bond line structure. HS 2. Draw bond-line (skeletal) structures for all constitutional isomers of C4H10. 3. Draw the bond-line structure for the following condensed structures: (CH3)2CHCH2OC(CH3)3 CH;CH2CH2COCH2CH3 (CH3)2CHCOOH2. Name the following molecules using IUPAC systematic naming, ignore stereochemistry. a. b. C. d. g. h. ex 8ء محكمه لار 3. Identify the hybridization (sp, sp2, sp³) of each carbon atom in the following molecules. } NH₂ 4. Identify the number of a bonds, bonds, lone pairs, and hydrogens in the following molecules. 8 1111 1111
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