1. (a). Gravimetric analysis is very useful for routine monitoring of ions present in relatively high concentrations. Why is gravimetric analysis not used for determining trace amounts of ions? (b). Discuss the sources of error in this experiment. 2. From 0.323 g of an unknown chloride sample (M-Cly), it produces 0.523 g of AgCl(s) solid under gravimetric analysis. What is the percentage of Cl- in the unknown sample? What is the theoretical molar weight of the metal in the chlorite salt sample M-Cly for the following given conditions? a. x = 1, y = 1; b. x = 1, y = 2; x = 2, y = 4. C.

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**Educational Content on Gravimetric Analysis**

**Discussion Questions**

1. **Gravimetric Analysis in Routine Monitoring:**
   - **(a)** Gravimetric analysis is highly effective for monitoring ions at relatively high concentrations. However, it is not suitable for determining trace amounts of ions. This limitation arises because gravimetric methods require sufficient quantities of the analyte to form a measurable precipitate. In trace scenarios, the amount of analyte may be too small to form a detectable precipitate, thus affecting accuracy and precision.
   
   - **(b)** Sources of error in gravimetric analysis can include incomplete precipitation, impurities in the precipitate, loss of precipitate during handling, or issues with the drying process. Each of these factors can lead to discrepancies between the observed and actual values.

2. **Analysis of Unknown Chloride Sample:**
   - From a sample weighing 0.323 g of an unknown chloride (represented as \( M_xCl_y \)), 0.523 g of silver chloride (\( \text{AgCl(s)} \)) solid is obtained through gravimetric analysis. The task is to determine the percentage of chlorine in the unknown sample and infer the theoretical molar weight of the metal in the chlorite salt sample \( M_xCl_y \) based on the conditions:
     - **a.** \( x = 1, y = 1 \)
     - **b.** \( x = 1, y = 2 \)
     - **c.** \( x = 2, y = 4 \) 

**Note:** This problem requires a detailed numerical analysis using the molecular weights of the elements involved and the stoichiometry dictated by the chemical formulas provided.
Transcribed Image Text:**Educational Content on Gravimetric Analysis** **Discussion Questions** 1. **Gravimetric Analysis in Routine Monitoring:** - **(a)** Gravimetric analysis is highly effective for monitoring ions at relatively high concentrations. However, it is not suitable for determining trace amounts of ions. This limitation arises because gravimetric methods require sufficient quantities of the analyte to form a measurable precipitate. In trace scenarios, the amount of analyte may be too small to form a detectable precipitate, thus affecting accuracy and precision. - **(b)** Sources of error in gravimetric analysis can include incomplete precipitation, impurities in the precipitate, loss of precipitate during handling, or issues with the drying process. Each of these factors can lead to discrepancies between the observed and actual values. 2. **Analysis of Unknown Chloride Sample:** - From a sample weighing 0.323 g of an unknown chloride (represented as \( M_xCl_y \)), 0.523 g of silver chloride (\( \text{AgCl(s)} \)) solid is obtained through gravimetric analysis. The task is to determine the percentage of chlorine in the unknown sample and infer the theoretical molar weight of the metal in the chlorite salt sample \( M_xCl_y \) based on the conditions: - **a.** \( x = 1, y = 1 \) - **b.** \( x = 1, y = 2 \) - **c.** \( x = 2, y = 4 \) **Note:** This problem requires a detailed numerical analysis using the molecular weights of the elements involved and the stoichiometry dictated by the chemical formulas provided.
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