1. a. Draw and name the five cycloalkane structures of formula C5H10. Can any of these structures give rise to geometric (cis-trans) isomerism? If so, show the cis and trans stereoisomers. b. Draw and name the eight cycloalkane structures of formula C6H12 that do not show geometric isomerism. c. Draw and name the four cycloalkanes of formula C6H12 that do have cis-trans isomers.

Introduction to General, Organic and Biochemistry
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Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter10: Organic Chemistry
Section: Chapter Questions
Problem 10.53P
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1. a. Draw and name the five cycloalkane structures of formula C5H10. Can any of these structures give rise to geometric (cis-trans) isomerism? If so, show the cis and trans stereoisomers.

b. Draw and name the eight cycloalkane structures of formula C6H12 that do not show geometric isomerism.

c. Draw and name the four cycloalkanes of formula C6H12 that do have cis-trans isomers.



2. Each of the following descriptions applies to more than one alkane. In each case, draw and name two structures that match the description.

(a) an isopropylheptane (b) a diethyldecane (c) a cis-diethylcyclohexane

(d) a trans-dihalocyclopentane (e) a (2,3-dimethylpentyl)cycloalkane (f) a bicyclononane

 


3. 2. refer to the photo attached and answer the ff.
3-33, 3-34

3-33
(a) There are 18 isomeric alkanes of molecular formula C3H18. Draw and name any eight of them.
(b) Draw and name the six isomeric cyclopentanes of molecular formula C,H14. These will include four constitutional
isomers, of which two show geometric (cis-trans) stereoisomerism.
Which of the following structures represent the same compound? Which ones represent different compounds?
3-34
(а)
H
H
H
нн
H
H.
H
CH3
CH, CH,
H
CH,
Н-С—С—С-Н Н—С—С
С—С—Н
Н-С—С-н
Н—С—С—Н
H-C-C-H
н СH,
СH, H
H
H
CH,
нн
H
H
H
H
(b)
(c)
CH,
CH,
„CH;
CH,
CH,
CH,
H
"CH,
"CH,
CH,
CH
H
H
(d)
Transcribed Image Text:3-33 (a) There are 18 isomeric alkanes of molecular formula C3H18. Draw and name any eight of them. (b) Draw and name the six isomeric cyclopentanes of molecular formula C,H14. These will include four constitutional isomers, of which two show geometric (cis-trans) stereoisomerism. Which of the following structures represent the same compound? Which ones represent different compounds? 3-34 (а) H H H нн H H. H CH3 CH, CH, H CH, Н-С—С—С-Н Н—С—С С—С—Н Н-С—С-н Н—С—С—Н H-C-C-H н СH, СH, H H H CH, нн H H H H (b) (c) CH, CH, „CH; CH, CH, CH, H "CH, "CH, CH, CH H H (d)
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