1. A voltaic cell consists of two half-cells. One of the half-cells contains a platinum electrode surrounded by chromium (II) and dichromate ions. The other half-cell contains a platinum electrode surrounded by

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1. A voltaic cell consists of two half-cells. One of the half-cells contains a platinum electrode surrounded
by chromium (III) and dichromate ions. The other half-cell contains a platinum electrode surrounded by
bromate ions and liquid bromine. Assume that the cell reaction, which produces a positive voltage,
involves both chromium (III) and bromate ions. The cell is at 25°C. Information for the bromate reduction
half reaction is as follows:
2BrО, (ag) + 12Hн (ад) + 10е-
Br2(1) + 6H,0
Eed = 1.478 V
(a) Write the cell diagram notation
(b) Calculate E° for the cell
(c) Calculate the voltage of the cell when all ionic species except H+ are 0.1500M and the pH is at -0.301.
2. Consider a voltaic cell at 25°C in which the following reaction takes place.
30,g) + 4NO(g) + 2H;0 → 4NO, (aq) + 4H* (aq)
(a) Calculate E° for the cell
(b) Calculate E under the following conditions: [NO:] = 0.750 M, PNo = 0.993 atm, Po, = 0.515 atm, pH =
2.85.
3. A metallurgist wants to goldplate a thin sheet with the following dimensions: 1.5 in. x 8.5 in. x 0.0012
in. The gold plating must be 0.0020 in. thick.
(a) How many grams of gold (p = 19.3 g/cm³) are required?
(b) How long will it take to place the sheet from AUCN using a current of 7.00 A? Assume 85% efficiency.
Transcribed Image Text:1. A voltaic cell consists of two half-cells. One of the half-cells contains a platinum electrode surrounded by chromium (III) and dichromate ions. The other half-cell contains a platinum electrode surrounded by bromate ions and liquid bromine. Assume that the cell reaction, which produces a positive voltage, involves both chromium (III) and bromate ions. The cell is at 25°C. Information for the bromate reduction half reaction is as follows: 2BrО, (ag) + 12Hн (ад) + 10е- Br2(1) + 6H,0 Eed = 1.478 V (a) Write the cell diagram notation (b) Calculate E° for the cell (c) Calculate the voltage of the cell when all ionic species except H+ are 0.1500M and the pH is at -0.301. 2. Consider a voltaic cell at 25°C in which the following reaction takes place. 30,g) + 4NO(g) + 2H;0 → 4NO, (aq) + 4H* (aq) (a) Calculate E° for the cell (b) Calculate E under the following conditions: [NO:] = 0.750 M, PNo = 0.993 atm, Po, = 0.515 atm, pH = 2.85. 3. A metallurgist wants to goldplate a thin sheet with the following dimensions: 1.5 in. x 8.5 in. x 0.0012 in. The gold plating must be 0.0020 in. thick. (a) How many grams of gold (p = 19.3 g/cm³) are required? (b) How long will it take to place the sheet from AUCN using a current of 7.00 A? Assume 85% efficiency.
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