1. A student mixes 5.00 mL 2.00 X 10-M Fe(NO,), in 1 M HNO, with 3.00 mL 2.00 x 10- M KSCN and 2.00 mL of water. She finds that in the equilibrium mixture the concentration of FeSCN?+ is 7.0 X 10 M. Find K, for the reaction Fe (aq) + SCN (aq) Fe(SCN)(aq).

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**Experiment 23**

**Advanced Study Assignment: Determination of the Equilibrium Constant for a Chemical Reaction**

---

1. A student mixes 5.00 mL of 2.00 x 10⁻³ M Fe(NO₃)₃ in 1 M HNO₃, with 3.00 mL of 2.00 x 10⁻³ M KSCN, and 2.00 mL of water. She finds that in the equilibrium mixture the concentration of FeSCN²⁺ is 7.0 x 10⁻⁵ M. Find \( K_c \) for the reaction \( \text{Fe}^{3+} \text{(aq)} + \text{SCN}^- \text{(aq)} \rightleftharpoons \text{FeSCN}^{2+} \text{(aq)} \).

**Step 1**: Find the number of moles of \( \text{Fe}^{3+} \) and \( \text{SCN}^- \) initially present. (Use Eq. 3)
- _______ moles \( \text{Fe}^{3+} \)
- _______ moles \( \text{SCN}^- \)

**Step 2**: How many moles of \( \text{FeSCN}^{2+} \) are in the mixture at equilibrium? What is the volume of the equilibrium mixture? (Use Eq. 3)
- _______ mL; _______ moles \( \text{FeSCN}^{2+} \)

How many moles of \( \text{Fe}^{3+} \) and \( \text{SCN}^- \) are used up in making the \( \text{FeSCN}^{2+} \)?
- _______ moles \( \text{Fe}^{3+} \)
- _______ moles \( \text{SCN}^- \)

**Step 3**: How many moles of \( \text{Fe}^{3+} \) and \( \text{SCN}^- \) remain in the solution at equilibrium? (Use Eq. 4 and the results of Steps 1 and 2.)
- _______ moles \( \text{Fe}^{3+} \)
- _______ moles \( \text{SCN}^- \)

**Step
Transcribed Image Text:**Experiment 23** **Advanced Study Assignment: Determination of the Equilibrium Constant for a Chemical Reaction** --- 1. A student mixes 5.00 mL of 2.00 x 10⁻³ M Fe(NO₃)₃ in 1 M HNO₃, with 3.00 mL of 2.00 x 10⁻³ M KSCN, and 2.00 mL of water. She finds that in the equilibrium mixture the concentration of FeSCN²⁺ is 7.0 x 10⁻⁵ M. Find \( K_c \) for the reaction \( \text{Fe}^{3+} \text{(aq)} + \text{SCN}^- \text{(aq)} \rightleftharpoons \text{FeSCN}^{2+} \text{(aq)} \). **Step 1**: Find the number of moles of \( \text{Fe}^{3+} \) and \( \text{SCN}^- \) initially present. (Use Eq. 3) - _______ moles \( \text{Fe}^{3+} \) - _______ moles \( \text{SCN}^- \) **Step 2**: How many moles of \( \text{FeSCN}^{2+} \) are in the mixture at equilibrium? What is the volume of the equilibrium mixture? (Use Eq. 3) - _______ mL; _______ moles \( \text{FeSCN}^{2+} \) How many moles of \( \text{Fe}^{3+} \) and \( \text{SCN}^- \) are used up in making the \( \text{FeSCN}^{2+} \)? - _______ moles \( \text{Fe}^{3+} \) - _______ moles \( \text{SCN}^- \) **Step 3**: How many moles of \( \text{Fe}^{3+} \) and \( \text{SCN}^- \) remain in the solution at equilibrium? (Use Eq. 4 and the results of Steps 1 and 2.) - _______ moles \( \text{Fe}^{3+} \) - _______ moles \( \text{SCN}^- \) **Step
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