1. A liquid mixture is sufficiently non-ideal that it forms a maximum- pressure azeotrope. If the pressure of the azeotrope is sufficiently larger than the saturation pressures of either component, the fugacity of either component can be greater than the pure component fugacity. Is the statement true or false? Explain the answer. 2. A binary mixture is in vapor-liquid equilibrium with 1 mol of liquid and 1 mol of vapor. The liquid forms an ideal solution, and Psat > Psat. When the pressure decreases at constant temperature, the fugacity of component 2 increases. Is the statement true or false? Explain the answer. 3. Given A₁ = a(n)vrnjji A, is called the partial molar Helmholtz free energy. Is the statement true or false? Explain the answer.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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1. A liquid mixture is sufficiently non-ideal that it forms a maximum-
pressure azeotrope. If the pressure of the azeotrope is sufficiently
larger than the saturation pressures of either component, the fugacity
of either component can be greater than the pure component fugacity.
Is the statement true or false? Explain the answer.
2. A binary mixture is in vapor-liquid equilibrium with 1 mol of liquid and 1
mol of vapor. The liquid forms an ideal solution, and Pșat > psat. When
the pressure decreases at constant temperature, the fugacity of
component 2 increases. Is the statement true or false? Explain the
answer.
3. Given A₁ = ((1)) v.1.n¡jzi
Ə(NA)`
ə(n₂),
A₁ is called the partial molar Helmholtz free energy. Is the statement
true or false? Explain the answer.
Transcribed Image Text:1. A liquid mixture is sufficiently non-ideal that it forms a maximum- pressure azeotrope. If the pressure of the azeotrope is sufficiently larger than the saturation pressures of either component, the fugacity of either component can be greater than the pure component fugacity. Is the statement true or false? Explain the answer. 2. A binary mixture is in vapor-liquid equilibrium with 1 mol of liquid and 1 mol of vapor. The liquid forms an ideal solution, and Pșat > psat. When the pressure decreases at constant temperature, the fugacity of component 2 increases. Is the statement true or false? Explain the answer. 3. Given A₁ = ((1)) v.1.n¡jzi Ə(NA)` ə(n₂), A₁ is called the partial molar Helmholtz free energy. Is the statement true or false? Explain the answer.
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