1. A liquid mixture containing 50 mol% propane, 30 mol% n-butane and 20 mol% isobutane is B stored in a rigid container at 25C. Parameters of Antoine equation Log,, p = A- are C+T given: A B C Propane n-Butane 4.5368 1149.4 24.91 4.3558 1175.6 -2.07 Isobutane 4.3281 1132.1 0.92

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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1. A liquid mixture containing 50 mol% propane, 30 mol% n-butane and 20 mol% isobutane is
B
stored in a rigid container at 25C. Parameters of Antoine equation Log,o p = A-
C+T
are
given:
A
В
1149.4 24.91
Propane
n-Butane
4.5368
4.3558
1175.6
-2.07
Isobutane 4.3281
1132.1
0.92
Units of vapour pressure (p*) and temperature (T) are in bar and K, respectively.
a) What is the total pressure of the vapour above liquid at 25°C?
b) Obtain a rough estimate of the temperature above which the maximum allowable pressure
of 200 psi would be exceeded. Comment on the suitability of the container to store the given
mixture.
Transcribed Image Text:1. A liquid mixture containing 50 mol% propane, 30 mol% n-butane and 20 mol% isobutane is B stored in a rigid container at 25C. Parameters of Antoine equation Log,o p = A- C+T are given: A В 1149.4 24.91 Propane n-Butane 4.5368 4.3558 1175.6 -2.07 Isobutane 4.3281 1132.1 0.92 Units of vapour pressure (p*) and temperature (T) are in bar and K, respectively. a) What is the total pressure of the vapour above liquid at 25°C? b) Obtain a rough estimate of the temperature above which the maximum allowable pressure of 200 psi would be exceeded. Comment on the suitability of the container to store the given mixture.
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