1. (a) Formulate four(4) different ways to synthesize 3-methylhexane from any readily available starting material. For each of these, show the reagent(s)required for each transformation, including all intermediates. (b) H.C. Brown used ester (2A) to test a new reducing agent which did indeed form alcohol (2B). How might he have made the ester (2A) from benzene. 2A C₂Me NaBH AICI3 2B CH₂OH (c) Suggest synthesis for the target molecules (3A) and (3B) needed as intermediates. TM (3A) in the synthesis of brominated hydroxybenzoic acids and TM (3B) in the synthesis of model compounds for studying biological mechanisms of ester hydrolysis. CO₂ OH CHO O₂N Br JL
1. (a) Formulate four(4) different ways to synthesize 3-methylhexane from any readily available starting material. For each of these, show the reagent(s)required for each transformation, including all intermediates. (b) H.C. Brown used ester (2A) to test a new reducing agent which did indeed form alcohol (2B). How might he have made the ester (2A) from benzene. 2A C₂Me NaBH AICI3 2B CH₂OH (c) Suggest synthesis for the target molecules (3A) and (3B) needed as intermediates. TM (3A) in the synthesis of brominated hydroxybenzoic acids and TM (3B) in the synthesis of model compounds for studying biological mechanisms of ester hydrolysis. CO₂ OH CHO O₂N Br JL
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Last two questions under 1 please
Transcribed Image Text:1. (a) Formulate four(4) different ways to synthesize 3-methylhexane from any
readily available starting material. For each of these, show the reagent(s)required
for each transformation, including all intermediates.
(b) H.C. Brown used ester (2A) to test a new reducing agent which did indeed
form alcohol (2B). How might he have made the ester (2A) from benzene.
2A
C₂Me
NaBH
AICI3
2B
CH₂OH
(c) Suggest synthesis for the target molecules (3A) and (3B) needed as intermediates.
TM (3A) in the synthesis of brominated hydroxybenzoic acids and TM (3B) in the
synthesis of model compounds for studying biological mechanisms of ester
hydrolysis.
CO₂
OH
CHO
O₂N
Br
JL
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