1. (a) 0.1 M HNO3 solution at 298K was electrolyzed in Hittorf cell using platinum electrodes. After electrolysis, 34.2 mg of copper was deposited in coulometer which in series with the Hittorf cell. 50 mL of HNO3 solution was withdrawn from anode compartment after electrolysis and found to have a concentration of 0.0821 M. [Atomic mass Cu 63]. (i) Find the transference number of H + and NO3 -. (ii) If 50 mL HNO3 solution was run off from cathode compartment, what would its concentration be?

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1. (a) 0.1 M HNO3 solution at 298K was
electrolyzed in Hittorf cell using platinum
electrodes. After electrolysis, 34.2 mg of
copper was deposited in coulometer which
in series with the Hittorf cell. 50 mL of
HNO3 solution was withdrawn from anode
compartment after electrolysis and found to
have a concentration of 0.0821 M. [Atomic
mass Cu = 63].
(i) Find the transference number of H + and
NO3 -.
(ii) If 50 mL HNO3 solution was run off from
cathode compartment, what would its
concentration be?
Transcribed Image Text:1. (a) 0.1 M HNO3 solution at 298K was electrolyzed in Hittorf cell using platinum electrodes. After electrolysis, 34.2 mg of copper was deposited in coulometer which in series with the Hittorf cell. 50 mL of HNO3 solution was withdrawn from anode compartment after electrolysis and found to have a concentration of 0.0821 M. [Atomic mass Cu = 63]. (i) Find the transference number of H + and NO3 -. (ii) If 50 mL HNO3 solution was run off from cathode compartment, what would its concentration be?
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