1. 2. a = Electrophilic addition mot b = E2 Elimination c = SN1 Nucleophilic substitution 1. 2. conc. HBr OEt KO-t-Bu d = SN2 Nucleophilic substitution e= Electrophilic aromatic substitution f = Carbonyl nucleophilic addn OH OEt ert Br Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g = Nucleophilic subs at carbonyl(acyl Xfer) h = Conjugate (nucleophilic) addn

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Match the mechanism with the letter listed
### Chemical Reaction Mechanism Identification

#### Reaction 1:
- **Starting Materials:** An alkene with an ether group. 
- **Reagents:** Concentrated HBr.
- **Products:** An alcohol and an alkyl bromide.

#### Reaction 2:
- **Starting Materials:** A cyclic ketone and an ethyl ester.
- **Reagents:** KO-t-Bu (potassium tert-butoxide).
- **Products:** A beta-keto ester with an extended carbon chain.

#### Mechanism Types:
- **a. Electrophilic addition**
- **b. E2 Elimination**
- **c. S<sub>N</sub>1 Nucleophilic substitution**
- **d. S<sub>N</sub>2 Nucleophilic substitution**
- **e. Electrophilic aromatic substitution**
- **f. Carbonyl nucleophilic addition**
- **g. Nucleophilic substitution at carbonyl (acyl transfer)**
- **h. Conjugate (nucleophilic) addition**

#### Task:
Identify the mechanism by which each of the reactions above proceeds from the listed mechanisms. Use the corresponding letter (a-h) for your answers.

1. [___]
2. [___]
Transcribed Image Text:### Chemical Reaction Mechanism Identification #### Reaction 1: - **Starting Materials:** An alkene with an ether group. - **Reagents:** Concentrated HBr. - **Products:** An alcohol and an alkyl bromide. #### Reaction 2: - **Starting Materials:** A cyclic ketone and an ethyl ester. - **Reagents:** KO-t-Bu (potassium tert-butoxide). - **Products:** A beta-keto ester with an extended carbon chain. #### Mechanism Types: - **a. Electrophilic addition** - **b. E2 Elimination** - **c. S<sub>N</sub>1 Nucleophilic substitution** - **d. S<sub>N</sub>2 Nucleophilic substitution** - **e. Electrophilic aromatic substitution** - **f. Carbonyl nucleophilic addition** - **g. Nucleophilic substitution at carbonyl (acyl transfer)** - **h. Conjugate (nucleophilic) addition** #### Task: Identify the mechanism by which each of the reactions above proceeds from the listed mechanisms. Use the corresponding letter (a-h) for your answers. 1. [___] 2. [___]
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