1) Na, CH3OH A. o-Xylene 2) NH3 1) R2NH, H", - H20 B. Cycloheptanone 2) EtHC-CHCOEt 3) НО +

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Chapter1: Chemical Foundations
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Give the organic Product structure and stereochemistry
**Chemical Reaction Processes**

_A. o-Xylene_

**Reagents:**
1. Na, CH₃OH
2. NH₃

_B. Cycloheptanone_

**Reagents:**
1. R₂NH, H⁺, - H₂O
2. EtHC=CHCOEt
3. H₃O⁺

**Explanation:**

**Section A: o-Xylene Reaction**
This chemical reaction involves o-xylene as the starting material. The reagents used for this transformation are sodium (Na), methanol (CH₃OH), and ammonia (NH₃). The arrow indicates a multi-step reaction that undergoes certain changes in the presence of these reagents.

**Section B: Cycloheptanone Reaction**
This section describes a reaction involving cycloheptanone. The process requires multiple steps and a sequence of reagents:
1. R₂NH (a secondary amine), H⁺ (a proton/hydrogen ion), and the removal of water (H₂O).
2. EtHC=CHCOEt (ethyl vinyl ketone).
3. H₃O⁺ (hydronium ion) for final protonation.

Both sections illustrate step-by-step transformations in organic chemistry involving complex reagents to achieve the desired product.
Transcribed Image Text:**Chemical Reaction Processes** _A. o-Xylene_ **Reagents:** 1. Na, CH₃OH 2. NH₃ _B. Cycloheptanone_ **Reagents:** 1. R₂NH, H⁺, - H₂O 2. EtHC=CHCOEt 3. H₃O⁺ **Explanation:** **Section A: o-Xylene Reaction** This chemical reaction involves o-xylene as the starting material. The reagents used for this transformation are sodium (Na), methanol (CH₃OH), and ammonia (NH₃). The arrow indicates a multi-step reaction that undergoes certain changes in the presence of these reagents. **Section B: Cycloheptanone Reaction** This section describes a reaction involving cycloheptanone. The process requires multiple steps and a sequence of reagents: 1. R₂NH (a secondary amine), H⁺ (a proton/hydrogen ion), and the removal of water (H₂O). 2. EtHC=CHCOEt (ethyl vinyl ketone). 3. H₃O⁺ (hydronium ion) for final protonation. Both sections illustrate step-by-step transformations in organic chemistry involving complex reagents to achieve the desired product.
### Reaction C

The chemical reaction follows three steps with the starting compound Ethyl nitrosacetate (EtCOCH₂NO₂):

1. **Reagent**: KOH (Potassium hydroxide)
2. **Reagent**: PhHC-CHCOOMe
3. **Reagent**: H₃O⁺ (Acidic work-up, often indicating hydronium ion or aqueous acid)

### Reaction D

Starting with **n-Valeraldehyde** and the reagent **(Ph₃)P-CHPh** (Triphenylphosphine benzylidine):

**n-Valeraldehyde + (Ph₃)P-CHPh → Product**

---

In both cases, the exact products are not specified in the image. 

* **Reaction C** implies a multi-step organic synthesis likely involving base catalysis (KOH), an intermediate reagent (PhHC-CHCOOMe), and then an acidic work-up (H₃O⁺).
* **Reaction D** suggests a Wittig reaction, typically used in organic chemistry to form alkenes from aldehydes and ketones.

Both reactions are indicative of complex organic synthesis involving key reagents and intermediates to transform given starting materials into desired end products.
Transcribed Image Text:### Reaction C The chemical reaction follows three steps with the starting compound Ethyl nitrosacetate (EtCOCH₂NO₂): 1. **Reagent**: KOH (Potassium hydroxide) 2. **Reagent**: PhHC-CHCOOMe 3. **Reagent**: H₃O⁺ (Acidic work-up, often indicating hydronium ion or aqueous acid) ### Reaction D Starting with **n-Valeraldehyde** and the reagent **(Ph₃)P-CHPh** (Triphenylphosphine benzylidine): **n-Valeraldehyde + (Ph₃)P-CHPh → Product** --- In both cases, the exact products are not specified in the image. * **Reaction C** implies a multi-step organic synthesis likely involving base catalysis (KOH), an intermediate reagent (PhHC-CHCOOMe), and then an acidic work-up (H₃O⁺). * **Reaction D** suggests a Wittig reaction, typically used in organic chemistry to form alkenes from aldehydes and ketones. Both reactions are indicative of complex organic synthesis involving key reagents and intermediates to transform given starting materials into desired end products.
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