1) MCPBA, CH,C2 2) H2O, cat. H,sO, 1) cat. OsO, tBuOOH, then NaOH/H,0 2) cat. TSOH, H,C CH, 1) cat. H,SO, ethylene glycol OH 2) DMSO, (COCI)2, EtgN, CH,Ci2 3) allyl magnesium bromide, THF, then H,0* workup 4) H20, HSO, heat H,C
1) MCPBA, CH,C2 2) H2O, cat. H,sO, 1) cat. OsO, tBuOOH, then NaOH/H,0 2) cat. TSOH, H,C CH, 1) cat. H,SO, ethylene glycol OH 2) DMSO, (COCI)2, EtgN, CH,Ci2 3) allyl magnesium bromide, THF, then H,0* workup 4) H20, HSO, heat H,C
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:1) MCPBA, CH,Cl2
2) H20, cat. H2sO,
1) cat. OsO, tBuOOH, then NaOH/H,O
2) cat. TSOH,
H,C
CH3
1) cat. H,SO4, ethylene glycol
2) DMSO, (COC)2, EtgN, CH,Cl2
3) allyi magnesium bromide, THF,
then H3O* workup
4) H20, H2SO, heat
H3C
но
OH
1) Nalo,
2) 1 equiv. CH3MgBr,
then H,O* workup
3) cat. HOAC,
H2N
Ph
H,C
PPh,
1) H;C
Ph'
2) MCPBA
3) Li-CEC-CH, , THF
then H30*
1) excess LIAIH., THF,
then H3O* workup
EtO
OEt
2) H3O* workup
3) cat. TSOH,
Ph
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