Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
- Structure: A cyclohexane ring with an OH group on the first carbon and another OH group on the third carbon.
2. 
- Structure: A cyclohexane ring with an OH group on the first carbon and another OH group on the second carbon.
3. 
- Structure: A cyclohexane ring with an OH group on the first carbon and a double-bonded oxygen (carbonyl) on the third carbon.
**Explanation of the Reaction:**
Lithium Aluminium Hydride (LiAlH₄) is a strong reducing agent commonly used to reduce carbonyl compounds to alcohols. Here, the cyclic ketone is reduced to a diol (a molecule with two hydroxyl groups).
- LiAlH₄ and diethyl ether (Et₂O) is the initial step, wherein the ketone is reduced. The reaction is then quenched with water (H₂O) in the second step to replace the Al-O species with H-O (hydroxyl groups).
- The reaction primarily targets the carbonyl group, resulting in a reduction to a secondary alcohol.
The correct structure of the major organic product is depicted in the options given.
**Identifying the Major Organic Product:**
Based on the reduction mechanism described, the product lacking the carbonyl group and showing two hydroxyl (OH) groups will be more favorable.
**Select Your Answer:**
Choose the correct structural formula for the major organic product below:
1. 
2. 
3. 
(This transcription and solution aim to clarify and analyze the given chemical reaction and potential synthetic outcomes for educational purposes.)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F650638ef-17d9-4755-bd2c-89f9558934a8%2Ffd15bb42-4b7e-4cbe-b117-bdcad38705fe%2Fctprghg_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Question:**
What is the major organic product?
**Reaction Details:**
The starting material is a cyclic ketone. The reaction involves:
1. Treatment with LiAlH₄ (Lithium Aluminium Hydride) in Et₂O (Diethyl Ether).
2. Followed by addition of H₂O (Water).
**Options for the major organic product:**
1. 
- Structure: A cyclohexane ring with an OH group on the first carbon and another OH group on the third carbon.
2. 
- Structure: A cyclohexane ring with an OH group on the first carbon and another OH group on the second carbon.
3. 
- Structure: A cyclohexane ring with an OH group on the first carbon and a double-bonded oxygen (carbonyl) on the third carbon.
**Explanation of the Reaction:**
Lithium Aluminium Hydride (LiAlH₄) is a strong reducing agent commonly used to reduce carbonyl compounds to alcohols. Here, the cyclic ketone is reduced to a diol (a molecule with two hydroxyl groups).
- LiAlH₄ and diethyl ether (Et₂O) is the initial step, wherein the ketone is reduced. The reaction is then quenched with water (H₂O) in the second step to replace the Al-O species with H-O (hydroxyl groups).
- The reaction primarily targets the carbonyl group, resulting in a reduction to a secondary alcohol.
The correct structure of the major organic product is depicted in the options given.
**Identifying the Major Organic Product:**
Based on the reduction mechanism described, the product lacking the carbonyl group and showing two hydroxyl (OH) groups will be more favorable.
**Select Your Answer:**
Choose the correct structural formula for the major organic product below:
1. 
2. 
3. 
(This transcription and solution aim to clarify and analyze the given chemical reaction and potential synthetic outcomes for educational purposes.)
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 1 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY