1 Consider a system consisting of gas 1 and gas 2 as shown in Fig.1. The two gases are separated by a movable, adiabatic wall, and they are in contact with an environment with temperature T through diathermal walls (i.e., isothermal condition). At the equilibrium, the volumes of the gas 1 and gas 2 are found to be V and V2, respectively. By using the free energy principle, show that the equilibrium condition is expressed as P(T,V)= P(T, V), where P and P2 represent the pressures of the gas 1 and gas 2, respectively. Environment with temperature T Fixed, diathermal wall Movable, adiabatic wall
1 Consider a system consisting of gas 1 and gas 2 as shown in Fig.1. The two gases are separated by a movable, adiabatic wall, and they are in contact with an environment with temperature T through diathermal walls (i.e., isothermal condition). At the equilibrium, the volumes of the gas 1 and gas 2 are found to be V and V2, respectively. By using the free energy principle, show that the equilibrium condition is expressed as P(T,V)= P(T, V), where P and P2 represent the pressures of the gas 1 and gas 2, respectively. Environment with temperature T Fixed, diathermal wall Movable, adiabatic wall
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Transcribed Image Text:1 Consider a system consisting of gas 1 and gas 2 as shown in Fig.1. The two
gases are separated by a movable, adiabatic wall, and they are in contact
with an environment with temperature T through diathermal walls (i.e.,
isothermal condition). At the equilibrium, the volumes of the gas 1 and
gas 2 are found to be Vi and V2, respectively. By using the free energy
principle, show that the equilibrium condition is expressed as
P(T, V) = P(T, V2),
%3D
where P and P2 represent the pressures of the gas 1 and gas 2, respectively.
Environment with
temperature T
Fixed,
diathermal wall
Movable,
adiabatic wall
Gas 1
Gas 2
Figure 1: Gas 1 and gas 2 separated by a movable, adiabatic wall,
and confined in a container under an isothermal condition.
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