1) (CH,CULI 2) CH) NaOH, HNMR 358 (s H) 124 (quintet, 1H) 2.1 (quintet, 1H) 20( 3H) 17 (sestet 12 (d, 3H) 1.1 (a, 3H) 0.9 (d, 3H) compound 2 HNMR 523 (quintet, 2H) 20 (s, ) 18 (sextet, 1H) 1.0 (d. GH) 0.9 (d, 3H) C NMR 8205, 57, 31, 28 18, 13 As shown above, treatment of the starting reactant first with lithium dimechylcopper ((CH32CULI) followed immediately by CHal affordec aqueous NAOH afforded compound Z (C1OH160) (its NMR data is also shown) by an intramolecular aldol condensation. What is the structure of the final product compound Z (C10H160)? Choose from the structures shown below.
1) (CH,CULI 2) CH) NaOH, HNMR 358 (s H) 124 (quintet, 1H) 2.1 (quintet, 1H) 20( 3H) 17 (sestet 12 (d, 3H) 1.1 (a, 3H) 0.9 (d, 3H) compound 2 HNMR 523 (quintet, 2H) 20 (s, ) 18 (sextet, 1H) 1.0 (d. GH) 0.9 (d, 3H) C NMR 8205, 57, 31, 28 18, 13 As shown above, treatment of the starting reactant first with lithium dimechylcopper ((CH32CULI) followed immediately by CHal affordec aqueous NAOH afforded compound Z (C1OH160) (its NMR data is also shown) by an intramolecular aldol condensation. What is the structure of the final product compound Z (C10H160)? Choose from the structures shown below.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1(CH,CuL
2) CH
NaOH,
HO
H NMR 358 (s. TH)
2.4 (quintet, 1H)
2.1 (quntet, 1H)
20(s 3H)
17 (sextet 1H
12 (d,3H)
1.1(d.3H)
compound 2
H NMR 5 2.3 (quintet, 2H)
20 (s, 611)
18 (sexlel 1H)
1.0 (d. 6H)
0.9 (d. 3H)
CHE P) 60
"C NMR 8 205, 57, 31, 28.
18, 13
As shown above, treatment of the starting reactant first with lithium dimethylcopper [(CHa)2CuLi) followed immediately by CH31 afforded a symmetrical, acyclic 1.5-diketone wich malecular formula CoH80, (its NMR data is shown). Treatment of this intermediate compound with
aqueous NaOH afforded compound Z (C10H160) (its NMR data is also shown) by an intramolecular aldol condensation.
What is the structure of the final product compound Z (C1oH160)? Choose from the structures shown below.
O A
O B
O D
O E
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