1- C-CI bond has a . . ( lower, higher) stretching frequency than C-Br bond

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Fill in the gaps withe the correct answer:
1- C-CI bond has a . ( lower, higher)
stretching frequency than C-Br bond
2- C=N bond has a . (lower, higher)
stretching frequency than C-N bond
3- The effect of conjugation on the frequency
. ( decreases, increases, doesn't effect ) the
frequency at which absorption occurs.
4- The chemical shift of the acid proton in the NMR
spectrum of
appears at.
.
HO-C-CH,
while the methyl protons ( in pink color) appears at
....
5- Give the structure of the Mc Lafferty
rearrangement product shown below:
CH3-CH-CH-C-CH,CH,CH3
+ alkene
m/z 100
6- Under kinetically controlled conditions, the
product with . ( higher, lower) activation
energy forms faster.
Transcribed Image Text:Fill in the gaps withe the correct answer: 1- C-CI bond has a . ( lower, higher) stretching frequency than C-Br bond 2- C=N bond has a . (lower, higher) stretching frequency than C-N bond 3- The effect of conjugation on the frequency . ( decreases, increases, doesn't effect ) the frequency at which absorption occurs. 4- The chemical shift of the acid proton in the NMR spectrum of appears at. . HO-C-CH, while the methyl protons ( in pink color) appears at .... 5- Give the structure of the Mc Lafferty rearrangement product shown below: CH3-CH-CH-C-CH,CH,CH3 + alkene m/z 100 6- Under kinetically controlled conditions, the product with . ( higher, lower) activation energy forms faster.
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