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1 A solution of silver nitrate containing 12.14 g of silver in 50 ml of soluti on was electrolysed between platinum electrodes. After electrolysis, 50 ml of the anode solution was found to contain 11.55g of silver, while 1.25 g of metallic silver was deposited on the cathode. Calculate the tran sference number of Ag+ and NO,-ions.

1 A solution of silver nitrate containing 12.14 g of silver in 50 ml of soluti on was electrolysed between platinum electrodes. After electrolysis, 50 ml of the anode solution was found to contain 11.55g of silver, while 1.25 g of metallic silver was deposited on the cathode. Calculate the tran sference number of Ag+ and NO,-ions.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Determine the Transference Number using the Hittorf's Method. 1 A solution of silver nitrate containing 12.14 g of silver in 50 ml of soluti on was electrolysed between platinum electrodes. After electrolysis, 50 ml of the anode solution was found to contain 11.55g of silver, while 1.25 g of metallic silver was deposited on the cathode. Calculate the tran sference number of Ag+ and NO,-jons. 2 In an electrolysis of copper sulphate between copper electrodes the total mass of copper deposited at the cathode was 0.153 g and the masses of copper per unit volume of the anode liquid before and after electrolysis were 0.79 and 0.91 g respectively. Calculate the transference number of the Cu2 and SO24- ions.
Transcribed Image Text:Determine the Transference Number using the Hittorf's Method. 1 A solution of silver nitrate containing 12.14 g of silver in 50 ml of soluti on was electrolysed between platinum electrodes. After electrolysis, 50 ml of the anode solution was found to contain 11.55g of silver, while 1.25 g of metallic silver was deposited on the cathode. Calculate the tran sference number of Ag+ and NO,-jons. 2 In an electrolysis of copper sulphate between copper electrodes the total mass of copper deposited at the cathode was 0.153 g and the masses of copper per unit volume of the anode liquid before and after electrolysis were 0.79 and 0.91 g respectively. Calculate the transference number of the Cu2 and SO24- ions.
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