Answered: 0.25 0.2 + f(E,T) kcal 0.15+ 0.1 mol…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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Question

The following figures show the energy distribution function at 300 K for the reaction A + B → CFor each figure, determine the following:
(a) What fraction of the collisions have energies between 3 and 5 kcal/mol?
(b) What fraction of collisions have energies greater than 5 kcal/mol?
(c) What is the fraction with energies greater than 0 kcal/mol?
(d) What is the fraction with energies 8 kcal/mol or greater?
(e) If the activation energy for Figure P3-5(b) is 8 kcal/mol, what fraction of molecules have an energy greater than E_A?
(f) Guess what (sketch) the shape of the curve f(E,T) versus E shown in Figure P3-5(b) would look like if the temperature were increased to 400 K.

0.25
0.2 +
f(E,T)
kcal
0.15+
0.1
mol
0.05
2 3 4 5 6 i
8.
E(kcal)/mol
T= 300 K
Figure P3-5(a)

0.25
0.2+
f(E,T)
0.15+
kcal
0.1
mol
0.05
10
E(kcalmol)
T= 300 K
Figure P3-5(b)

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